Insertion of Amides into a Polyoxometalate

被引：57

作者：

Li, Joaquim ^{[1
]}

Huth, Inga ^{[1
]}

Chamoreau, Lise-Marie ^{[1
]}

Hasenknopf, Bernold ^{[1
]}

Lacote, Emmanuel ^{[1
]}

Thorimbert, Serge ^{[1
]}

Malacria, Max ^{[1
]}

机构：

[1] Univ Paris 06, CNRS, UMR 7201, Inst Parisien Chim Mol, F-75005 Paris, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 11期

关键词：

organic-inorganic hybrid composites; polyoxometalates; substituent effects; vanadates; STRUCTURAL-CHARACTERIZATION; O-ACYLATION; HETEROPOLYANIONS; DAWSON; HETEROPOLYMOLYBDATES; ASSEMBLIES; CATALYSIS; CLUSTERS; LIGANDS; POLYMER;

D O I：

10.1002/anie.200805964

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) POM alert: The incorporation of an amide oxygen atom into the framework of the Dawson-type polyoxometalate (POM) cluster [P 2V3W15O62]9- (see picture) allows the communication of electronic effects between the organic and the inorganic parts of the molecule, including fine-tuning of the redox properties of the entire hybrid POM by the organic components, and transmission of the POM's electron-attracting properties to the organic moiety. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2035 / 2038

页数：4

相关论文

共 50 条

[1] Hybrid organic-inorganic porphyrin-polyoxometalate complexes [J].

Allain, Clemence ;

Favette, Sophie ;

Chamoreau, Lise-Marie ;

Vaissermann, Jacqueline ;

Ruhlmann, Laurent ;

Hasenknopf, Bernold .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (22) :3433-3441

[2]

[Anonymous], 2000, ANGEW CHEM-GER EDIT

[3] Regioselective activation of oxo ligands in functionalized Dawson polyoxotungstates [J].

Boglio, Cecile ;

Micoine, Kevin ;

Derat, Etienne ;

Thouvenot, Rene ;

Hasenknopf, Bernold ;

Thorimbert, Serge ;

Lacote, Emmanuel ;

Malacria, Max .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (13) :4553-4561

[4] Lindqvist-type (aryldiazenido)polyoxomolybdates -: Synthesis, and structural and spectroscopic characterization of compounds of the type (nBu4N)3[Mo6O18(N2Ar)] [J].

Bustos, C ;

Hasenknopf, B ;

Thouvenot, R ;

Vaissermann, J ;

Proust, A ;

Gouzerh, P .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (15) :2757-2766

[5] FORMATION OF AN OXALATE-FILLED CAVITY IN A REDUCED CYCLIC OCTANUCLEAR POLYOXOMOLYBDATE [(N-C4H9)4N]2[MO8O16(OCH3)8(C2O4)] FORMED FROM ALPHA-(N-C4H9)4N]4[MO8O26] AND RHODIZONIC ACID [J].

CHEN, Q ;

LIU, SC ;

ZUBIETA, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (12) :1724-1725

[6] A CYCLIC OCTANUCLEAR POLYOXOALKOXYVANADATE(IV) WITH AN OXALATE-BINDING CAVITY, [(N-C4H9)4N]2[V8O8(OCH3)16(C2O4)] - STRUCTURAL COMPARISON WITH THE ANALOGOUS POLYMOLYBDATE(V) COMPLEX [(N-C4H9)4N]2[MO8O16(OC2H5)8(C2O4)] [J].

CHEN, Q ;

LIU, SC ;

ZUBIETA, J .

INORGANIC CHEMISTRY, 1989, 28 (25) :4433-4434

[7] COORDINATION-COMPOUNDS OF POLYOXOVANADATES WITH A HEXAMETALATE CORE - CHEMICAL AND STRUCTURAL CHARACTERIZATION OF [V(V)6O13((OCH2)3CR(2]2-, [V(V)6O11(OH)2((OCH2)3CR(2], [V(IV)4V(V)2O9(OH)4((OCH2)3CR(2]2-, AND [V(IV)6O7(OH)6((OCH2)3CR(2]2- [J].

CHEN, Q ;

GOSHORN, DP ;

SCHOLES, CP ;

TAN, XL ;

ZUBIETA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) :4667-4681

[8]

CHEN Q, 1988, ANGEW CHEM, V100, P1792

[9] Recent advances in polyoxometalate-containing molecular conductors [J].

Coronado, E ;

Giménez-Saiz, C ;

Gómez-García, CJ .

COORDINATION CHEMISTRY REVIEWS, 2005, 249 (17-18) :1776-1796

[10] NONAQUEOUS ROUTES TO A NEW POLYOXOTUNGSTATE [J].

ERRINGTON, RJ ;

KERLOGUE, MD ;

RICHARDS, DG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (07) :649-651

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