An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

被引：73
作者：
Xie, Jingfan [1 ,2 ]
Zhou, Qianxiong [1 ]
Li, Chao [1 ]
Wang, Weibo [1 ]
Hou, Yuanjun [1 ]
Zhang, Baowen [1 ]
Wang, Xuesong [1 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 49期
关键词：
MOLYBDENUM-OXO CATALYST; H-2; PRODUCTION; ELECTROCHEMICAL GENERATION; AQUEOUS-SOLUTIONS; WATER; EVOLUTION; REDUCTION;
D O I：
10.1039/c4cc01471e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.
引用
收藏
页码：6520 / 6522
页数：3
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