An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

被引：73

作者：

Xie, Jingfan ^{[1
,2
]}

Zhou, Qianxiong ^{[1
]}

Li, Chao ^{[1
]}

Wang, Weibo ^{[1
]}

Hou, Yuanjun ^{[1
]}

Zhang, Baowen ^{[1
]}

Wang, Xuesong ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 49期

关键词：

MOLYBDENUM-OXO CATALYST; H-2; PRODUCTION; ELECTROCHEMICAL GENERATION; AQUEOUS-SOLUTIONS; WATER; EVOLUTION; REDUCTION;

D O I：

10.1039/c4cc01471e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.

引用

页码：6520 / 6522

页数：3

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