Light-induced frequency shift in chemical spirals

被引：36

作者：

Petrov, V

Qi, OY

Li, G

Swinney, HL

机构：

[1] UNIV TEXAS,CTR NONLINEAR DYNAM,AUSTIN,TX 78712

[2] UNIV TEXAS,DEPT PHYS,AUSTIN,TX 78712

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期

关键词：

D O I：

10.1021/jp961392s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Illumination of ruthenium-catalyzed Belousov-Zhabotinsky reaction decreases the rotational frequency of spirals at low bromate concentrations but increases the frequency at high bromate concentrations. The effective diffusion coefficient D deduced from the Keener-Tyson relation for the spirals, D approximate to omega/3k(2), is independent of light intensity (D = 2.5 x 10(-6) cm(2)/s).

引用

页码：18992 / 18996

页数：5

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