Enhancement of thermoelectric properties by Se substitution in layered bismuth-chalcogenide LaOBiS2-xSex

被引:52
作者
Mizuguchi, Yoshikazu [1 ]
Omachi, Atsushi [1 ]
Goto, Yosuke [2 ]
Kamihara, Yoichi [2 ]
Matoba, Masanori [2 ]
Hiroi, Takafumi [1 ]
Kajitani, Joe [1 ]
Miura, Osuke [1 ]
机构
[1] Tokyo Metropolitan Univ, Dept Elect & Elect Engn, Hachioji, Tokyo 1920397, Japan
[2] Keio Univ, Dept Appl Phys & Physicoinformat, Yokohama, Kanagawa 2238522, Japan
关键词
SUPERCONDUCTIVITY; POWER;
D O I
10.1063/1.4900953
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have investigated the thermoelectric properties of the novel layered bismuth chalcogenides LaOBiS2-xSex. The partial substitution of S by Se produced the enhancement of electrical conductivity (metallic characteristics) in LaOBiS2-xSex. The power factor largely increased with increasing Se concentration. The highest power factor was 4.5 mu W/cmK(2) at around 470 degrees C for LaOBiS1.2Se0.8. The obtained dimensionless figure-of-merit (ZT) was 0.17 at around 470 degrees C in LaOBiS1.2Se0.8. (C) 2014 AIP Publishing LLC.
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页数:4
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