Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X

被引：10

作者：

Frohn, HJ ^{[1
]}

Bardin, VV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST ORGAN CHEM,NOVOSIBIRSK 630090,RUSSIA

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 07期

关键词：

xenon difluoride; electrophilic oxygenation; polyfluorobenzenes; polyfluorinated 1,4-cyclohexadienones; epoxidation;

D O I：

10.1515/znb-1996-0718

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrophilic oxygenation of polyfluorobenzenes C6F5 X (X = F, Cl, Br, H, CF3, NH3+, NMe(3)(+), OH and OCH2CF3) with XeF2 and H2O in HF leads to the formation of polyfluorinated 1,4-cyclohexadienones. Pentafluoroiodobenzene is converted into C6F5IF2 and C6F5IF4, whereas [C6F5N2](+) [NbF6](-) is unreactive towards this new type of electrophilic oxygenation.

引用

页码：1015 / 1021

页数：7

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