μ-Biphenyl-2,2′-dithiolato-κ2S:S′-bis[(triphenylphosphine-κP)gold(I)]

被引：1
作者：
Larkin, SA
Bauer, JAK
Konoplev, VE
Dyadchenko, VP
Lemenovskii, DA
Bruce, MRM [1 ]
Bruce, AE
机构：
[1] Univ Maine, Dept Chem, Orono, ME 04469 USA
[2] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷 / 09期
关键词：
D O I：
10.1107/S0108270104016099
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of ClAuPPh3 and 1,1'-biphenyl-2,2'-dithiol in the presence of trimethylbenzylammonium chloride and K2CO3 in a tetrahydrofuran/methanol solution gives the title complex, [Au-2(C12H8S2)(C18H15P)(2)]. The molecule contains P-Au-S units which 'cross' with torsion angles of similar to90degrees [P-Au-Au-P = 86.23 (5)degrees and S-Au-Au-S = 95.62 (5)degrees]. The intra- and intermolecular Au...Au distances [3.9064 (3) and 6.3797 (5) Angstrom, respectively] are outside the range for typical Au...Au interactions. However, the Au atoms appear to be drawn together, leading to a significant bending of the P-Au-S angles [170.24 (5) and 169.52 (5)degrees].
引用
收藏
页码：M440 / M442
页数：3
相关论文
共 50 条
  • [31] A quadrupole-quadrupole stacking synthon in (2,3,5,6-tetrafluorobenzenethiolato-κS)(triphenylphosphine-κP)gold(I)
    Watase, S
    Kitamura, T
    Kanehisa, N
    Nakamoto, M
    Kai, Y
    Yanagida, S
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : M104 - M106
  • [32] N,N′-Bis(4-bromobenzylidene)biphenyl-2,2′-diamine
    Dehghanpour, Saeed
    Asadizadeh, Saeedeh
    Gao, Shan
    Ng, Seik Weng
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O306 - U2020
  • [33] N,N′-Bis(4-nitrophenyl)biphenyl-2,2′-dicarboxamide
    Wang, Gui-Yu
    Qin, Da-Bin
    Guo, Li-Hui
    Luo, Jie-Wei
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O644 - U5263
  • [34] N,N′-Bis(3-phenylallylidene)biphenyl-2,2′-diamine
    Dehghanpour, Saeed
    Afshariazar, Farzaneh
    Gao, Shan
    Ng, Seik Weng
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O307 - U2027
  • [35] (μ-Pyridine-2-carbaldehyde azine)bis[bis(triphenylphosphine-κP)copper(I)] bis(tetrafluoridoborate) dichloromethane disolvate
    Yang, Li
    Xie, Yu
    Zou, Jianping
    Jia, Jie
    Hong, Xiaowei
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1017 - U1760
  • [36] (Dithiobenzoato-κ2S,S′)[hydridotris-(pyrazol-1-yl-κN2)borato]( triphenylphosphine-κP)ruthenium(II)
    Lin, Chia-Her
    Liang, Yao-Ren
    Tong, Hung-Chun
    Lo, Yih Hsing
    Kuo, Ting Shen
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1535 - U524
  • [37] [Bis(3,5-dimethylpyrazol-1-yl-κN2)dithioacetato-κS](triphenylphosphine-κP)copper(I)
    Liu, Lei-Lei
    Tang, Xiao-Yan
    Li, Hong-Xi
    Zhang, Yong
    Lang, Jian-Ping
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2007, 63 (m513-m515): : M513 - M515
  • [38] Chlorido(1,3-dimethylthiourea-κS)bis(triphenylphosphine-κP)copper(I) acetonitrile hemisolvate
    La-O, Latipah
    Pakawatchai, Chaveng
    Saithong, Saowanit
    Skelton, Brian W.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M926 - U985
  • [39] Dicarbonyl(pyrazine-1,3-dithiolato-κ2S,S′)bis(trimethylphosphane-κP)iron(II)
    Gao, Shang
    Duan, Qian
    An, Chun-ai
    Jiang, Da-yong
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1790 - U1367
  • [40] (Piperidine-1-carbodithioato-S,S′)-bis (triphenylphosphine-P)gold(I)
    Razak, Ibrahim Abdul
    Raj, S. Shanmuga Sundara
    Fun, Hoong-Kun
    Jian, Fangfang
    Bei, Fengli
    Yang, Xujie
    Lu, Lude
    Wang, Xin
    [J]. 2000, Munksgaard Int Publ. Ltd., Copenhagen K, Denmark (56)
12345