μ-Biphenyl-2,2′-dithiolato-κ2S:S′-bis[(triphenylphosphine-κP)gold(I)]

被引：1
|
作者：
Larkin, SA
Bauer, JAK
Konoplev, VE
Dyadchenko, VP
Lemenovskii, DA
Bruce, MRM [1 ]
Bruce, AE
机构：
[1] Univ Maine, Dept Chem, Orono, ME 04469 USA
[2] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷 / 09期
关键词：
D O I：
10.1107/S0108270104016099
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of ClAuPPh3 and 1,1'-biphenyl-2,2'-dithiol in the presence of trimethylbenzylammonium chloride and K2CO3 in a tetrahydrofuran/methanol solution gives the title complex, [Au-2(C12H8S2)(C18H15P)(2)]. The molecule contains P-Au-S units which 'cross' with torsion angles of similar to90degrees [P-Au-Au-P = 86.23 (5)degrees and S-Au-Au-S = 95.62 (5)degrees]. The intra- and intermolecular Au...Au distances [3.9064 (3) and 6.3797 (5) Angstrom, respectively] are outside the range for typical Au...Au interactions. However, the Au atoms appear to be drawn together, leading to a significant bending of the P-Au-S angles [170.24 (5) and 169.52 (5)degrees].
引用
收藏
页码：M440 / M442
页数：3
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