Reaction of palladium bis(acetylacetonate) with diphenylphosphine: Spectral studies

被引：7

作者：

Belykh, LB ^{[1
]}

Goremyka, TV ^{[1
]}

Zinchenko, SV ^{[1
]}

Rokhin, AV ^{[1
]}

Ratovskii, GV ^{[1
]}

Schmidt, FK ^{[1
]}

机构：

[1] Irkutsk State Univ, Irkutsk 664003, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 28卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/A:1020099201962

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interaction of palladium bis(acetylacetonate) with diphenylphosphine is studied by NMR, IR, and UV methods. Reaction between reagents taken in equimolar amounts gives binuclear and trinuclear palladium complexes with bridging diphenylphosphide and the chelate acetylacetonate [Pd(Acac)PPh2](2) and [Pd-3(Acac)(2)(PPh2)(4)] ligands. With excess PPh2H, the trinuclear palladium complex, whose composition is supposed to be [Pd-3(PPh2)(4)(PPh2-PPh2) . C6H6], is isolated and characterized on the basis of the spectral data.

引用

页码：664 / 669

页数：6

共 21 条

[11] Oxidative addition of dimesitylphosphine to platinum(0): P-H vs P-C activation [J].