Effect of hydrogen transfer reaction on kinetics of nitroxide-mediated free-radical polymerization

被引：46
|
作者：
He, JP [1 ]
Li, L [1 ]
Yang, YL [1 ]
机构：
[1] Fudan Univ, Key Lab Mol Engn Polymers, State Educ Minist, Dept Macromol Sci, Shanghai 200433, Peoples R China
来源：
MACROMOLECULES | 2000年 / 33卷 / 06期
关键词：
D O I：
10.1021/ma991354h
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The effect of hydrogen transfer reactions on the kinetics and molecular weight distribution of nitroxide-mediated radical polymerization was studied by Monte Carlo simulation. It was found that the hydrogen transfer reaction not only reduced the polymerization rate but also broadened the contribution of the product.
引用
收藏
页码：2286 / 2289
页数：4
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