Passive and electrochemical response of friction stir processed pure Titanium

被引：60

作者：

Fattah-alhosseini, Arash ^{[1
]}

Vakili-Azghandi, Mojtaba ^{[1
]}

Sheikhi, Mohsen ^{[1
]}

Keshavarz, Mohsen K. ^{[2
]}

机构：

[1] Bu Ali Sina Univ, Dept Mat Engn, Hamadan 6517838695, Iran

[2] McGill Univ, Dept Min & Mat Engn, Quebec City, PQ H3A 0C5, Canada

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2017年 / 704卷

关键词：

Pure Ti; Friction stir processing; Grain refinement; Passive behavior; Phosphate buffer solution; Mott-Schottky analysis; CORROSION-RESISTANCE; BEHAVIOR; ALLOYS; TEXTURE; TESTS;

D O I：

10.1016/j.jallcom.2017.02.095

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present work, the effects of multi-pass friction stir processing on the passive behavior and electrochemical response of pure Titanium in a phosphate buffer solution (pH = 10.69) were studied. Microstructures of treated and untreated samples were characterized using scanning electron microscopy. Results showed that with increasing the number of passes of the friction stir process, finer microstructure was obtained. Electrochemical tests, including potentiodynamic polarization measurements and electrochemical impedance spectroscopy, showed that the friction stir processed sample provided a superior passive behavior with highest corrosion resistance among all samples in the phosphate buffer solution. These enhancements can be ascribed to the development of the various defects in the structural and grain refinement induced by friction stir processing. Moreover, Mott-Schottky test was performed to assess the semiconducting properties of passive layers. It was found that the semiconducting behavior remained the same upon friction stir processing, but reduced the electron donor density and provided an additional donor level. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：499 / 508

页数：10

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