X-ray photoelectron study on gold/nanocrystalline cellulose-graphene oxide thin film as surface plasmon resonance active layer for metal ion detection

被引：14

作者：

Daniyal, Wan Mohd Ebtisyam Mustaqim Mohd ^{[1
]}

Fen, Yap Wing ^{[1
,2
]}

Abdullah, Jaafar ^{[1
]}

Hashim, Hazwani Suhaila ^{[2
]}

Fauzi, Nurul 'Illya Muhamad ^{[2
]}

Chanlek, Narong ^{[3
]}

Mahdi, Mohd Adzir ^{[4
]}

机构：

[1] Univ Putra Malaysia, Inst Adv Technol, Serdang 43400, Selangor, Malaysia

[2] Univ Putra Malaysia, Dept Phys, Fac Sci, Serdang 43400, Selangor, Malaysia

[3] Synchrotron Light Res Inst, Nakhon Ratchasima 30000, Thailand

[4] Univ Putra Malaysia, Fac Engn, Wireless & Photon Networks, Serdang 43400, Selangor, Malaysia

来源：

THIN SOLID FILMS | 2020年 / 713卷

关键词：

X-ray photoelectron spectroscopy; Nanocrystalline cellulose; Graphene oxide; Surface plasmon resonance; OPTICAL SENSOR; REFRACTIVE-INDEX; NANOCRYSTALS; COPPER; ZINC; MONOLAYER; WHISKERS;

D O I：

10.1016/j.tsf.2020.138340

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

X-ray photoelectron spectroscopy (XPS) is a spectroscopic technique that is surface-sensitive that can be used to analyze the chemical and elemental state of a sample on the surface. In this research, XPS was used to study the chemical interaction of gold/nanocrystalline cellulose-graphene oxide (gold/NCC-GO) thin film. The thin film was prepared by deposition of NCC-GO on a gold thin film using spin coating method to obtain a homogeneous gold/NCC-GO thin film before characterized by XPS. From the XPS results, it is confirmed that carbon, oxygen, nitrogen, and sulfur elements exist on the gold/NCC-GO thin film surface. Further deconvolution has also been carried out by Voigt curve fitting program in order to determine the sub-peak component of each elements. Besides that, the gold/NCC-GO thin film has potential to be used in sensing metal ion application. The interaction of metal ions with the gold/NCC-GO thin film was optically proven using surface plasmon resonance optical sensor before the thin film was characterized again by XPS to confirm the chemical interactions involved. It is believed that the existence negative charge functional groups, i.e., COO- and SO3- on the gold/NCC-GO thin film surface played an important role during the interaction.

引用

页数：10

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[1] Surface modification of cellulose nanocrystals with cetyltrimethylammonium bromide [J].