Reduced graphene oxide decorated with Fe doped SnO2 nanoparticles for humidity sensor

被引:96
作者
Toloman, D. [1 ]
Popa, A. [1 ]
Stan, M. [1 ]
Socaci, C. [1 ]
Biris, A. R. [1 ]
Katona, G. [2 ]
Tudorache, F. [3 ,4 ]
Petrila, I. [3 ,4 ,5 ]
Iacomi, F. [6 ]
机构
[1] Natl Inst Res & Dev Isotop & Mol Technol, 67-103 Donat St, Cluj Napoca 400293, Romania
[2] Univ Babes Bolyai, Fac Chem & Chem Engn, 11 Arany Janos St, Cluj Napoca 400028, Romania
[3] Alexandru Ioan Cuza Univ, Interdisciplinary Res Dept Field Sci, 11 Carol 1 Blvd, Iasi 7000506, Romania
[4] Alexandru Ioan Cuza Univ, RAMTECH, 11 Carol 1 Blvd, Iasi 7000506, Romania
[5] Gheorghe Asachi Tech Univ, Fac Automat Control & Comp Engn, 27 Dimitrie Mangeron St, Iasi 700050, Romania
[6] Alexandru Ioan Cuza Univ, Fac Phys, 11 Carol 1 Blvd, Iasi 7000506, Romania
关键词
Nanoparticles; Reduced graphene oxide; Composites; Humidity sensor; GAS-SENSING PROPERTY; ELECTRICAL-PROPERTIES; FERRITE MATERIAL; WATER-VAPOR; TIN DIOXIDE; THIN-FILMS; PERFORMANCE; MICROSTRUCTURE; TEMPERATURE; FABRICATION;
D O I
10.1016/j.apsusc.2017.01.064
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Reduced graphene oxide (rGO) decorated with Fe doped SnO2 nanoparticles were fabricated via the electrostatic interaction between positively charged modified Fe-doped SnO2 oxide and negatively charged graphene oxide (GO) in the presence of poly(allylamine) hydrochloride (PAH). The decoration of rGO layers with SnO2:Fe nanoparticles was highlited by TEM microsopy. For composite sample the diffraction patterns coincide well with those of SnO2:Fe nanoparticles. The reduction of graphene oxide was evidenced using XRD and FT-IR spectroscopy. The formation of SnO2:Fe-PAH-graphene composites was confirmed by FT-IR, Raman and EPR spectroscopy. Sensitivity tests for relative humidity (RH) measurements were carried out at five different concentrations of humid air at room temperature. The prepared composite sensor exhibited a higher sensing response as compared with Fe:SnO2 nanoparticles. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:410 / 417
页数:8
相关论文
共 48 条
[1]   The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption Spectroscopy [J].
Acik, Muge ;
Lee, Geunsik ;
Mattevi, Cecilia ;
Pirkle, Adam ;
Wallace, Robert M. ;
Chhowalla, Manish ;
Cho, Kyeongjae ;
Chabal, Yves .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (40) :19761-19781
[2]   Preparation and characterizations of SnO2 nanopowder and spectroscopic (FT-IR, FT-Raman, UV-Visible and NMR) analysis using HF and DFT calculations [J].
Ayeshamariam, A. ;
Ramalingam, S. ;
Bououdina, M. ;
Jayachandran, M. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 118 :1135-1143
[3]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[4]   Humidity sensors: A review of materials and mechanisms [J].
Chen, Z ;
Lu, C .
SENSOR LETTERS, 2005, 3 (04) :274-295
[5]   Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G ;
Pan, ZW ;
Wang, ZL .
APPLIED PHYSICS LETTERS, 2002, 81 (10) :1869-1871
[6]   Vanadium doped tin dioxide as a novel sulfur dioxide sensor [J].
Das, S. ;
Chakraborty, S. ;
Parkash, O. ;
Kumar, D. ;
Bandyopadhyay, S. ;
Samudrala, S. K. ;
Sen, A. ;
Maiti, H. S. .
TALANTA, 2008, 75 (02) :385-389
[7]   Fabrication of Fe3O4@reduced graphene oxide composite via novel colloid electrostatic self-assembly process for removal of contaminants from water [J].
Ding, Jie ;
Li, Baojun ;
Liu, Yushan ;
Yan, Xiaoshe ;
Zeng, Sha ;
Zhang, Xudong ;
Hou, Lifen ;
Cai, Qiang ;
Zhang, Jianmin .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (02) :832-839
[8]   P-n junction characteristics of graphene oxide and reduced graphene oxide on n-type Si(111) [J].
Duy-Thach Phan ;
Chung, Gwiy-Sang .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2013, 74 (11) :1509-1514
[9]   Pd-WO3/reduced graphene oxide hierarchical nanostructures as efficient hydrogen gas sensors [J].
Esfandiar, Ali ;
Irajizad, Azam ;
Akhavan, Omid ;
Ghasemi, Shahnaz ;
Gholami, Mohammad Reza .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (15) :8169-8179
[10]   DRIFT studies of thick film un-doped and Pd-doped SnO2 sensors:: temperature changes effect and CO detection mechanism in the presence of water vapour [J].
Harbeck, S ;
Szatvanyi, A ;
Barsan, N ;
Weimar, U ;
Hoffmann, V .
THIN SOLID FILMS, 2003, 436 (01) :76-83