STUDY OF THE RANITIDINE DEGRADATION BY H2O2 ELECTROGENERATED/FENTON IN A ELECTROCHEMICAL REACTOR WITH GAS DIFFUSION ELECTRODE

被引:20
作者
Beati, Andre A. G. F. [1 ]
Rocha, Robson S. [1 ]
Oliveira, Joaquim G. [2 ]
Lanza, Marcos R. V. [2 ]
机构
[1] Univ Estadual Campinas, Fac Engn Mecan, Dept Mat Engn, CP 6122, BR-13083970 Campinas, SP, Brazil
[2] Univ Sao Francisco Assis, Lab Pesquisas Eletroquim & Eletroanalit, BR-12916900 Braganca Paulista, SP, Brazil
来源
QUIMICA NOVA | 2009年 / 32卷 / 01期
关键词
ranitidine degradation; hydrogen peroxide; gas diffusion electrodes; FED GRAPHITE/PTFE ELECTRODES; SEWAGE-TREATMENT PLANTS; HYDROGEN-PEROXIDE; RESISTANCE; DRUGS;
D O I
10.1590/S0100-40422009000100024
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The study of the electrochemical degradation of the ranitidine was developed using an electrochemical reactor with a gas diffusion electrode (GDE) as cathode. The electrolysis experiments was performed at constant current (1 <= A <= 10) and flow rate of 200 L h(-1). The process of drug degradation, chemical/electrochemical and electro-Fenton ways, using electrochemical reactor showed best efficiency at current values of >= 4 A. The process reached a production of 630 mg L-1 of the H2O2 at 7 A. The ranitidine concentrations was reduced in 99.9% (HPLC) and chemical oxygen demand (COD) was reduced in 86.7% by electro-Fenton.
引用
收藏
页码:125 / 130
页数:6
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