Electron-impact-induced fragmentation of diazodiarylmethanes

被引:0
作者
Kuruc, J [1 ]
Kardosova, E [1 ]
Rodina, LL [1 ]
机构
[1] ST PETERSBURG STATE UNIV,DEPT CHEM,ST PETERSBURG 199034,RUSSIA
来源
CHEMICKE LISTY | 1997年 / 91卷 / 09期
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electron-impact-induced fragmentation (the mass spectra, 15-70 eV) of diazodiarylmethanes (diazodiphenylmethane, phenyl-para-methoxyphenyldiazomethane, phenyl-para-biphenyldiazomethane, 10-diazonaphtoquinone, and 9-diazathiaxanthene), was studied. For all investigated diazocompounds fragmentational schemes were proposed. All diazodiarylmethanes show molecular ion with 1.6-30.4 % of relative abundance. A typical fragments are [M-C](+), [M-N](+), [M-N-2](+), [M-C-N](+) and [M-C-N-2](+).
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页码:778 / 779
页数:2
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