Cyclopropane formation under frustrated Lewis pair conditions

被引：4
作者：
Krupski, Sergei [1 ]
Kehr, Gerald [1 ]
Daniliuc, Constantin G. [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, Corrensstr 40, D-48149 Munster, Germany
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 13期
基金：
欧洲研究理事会;
关键词：
CHEMISTRY; BORANE; DIHYDROGEN; ACTIVATION; FEATURES; ADDUCT; STATE; ACID;
D O I：
10.1039/c5cc09585a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of the -CH2OSiMe3 substituted allyldimesitylphosphane 5 with HB(C6F5)(2) resulted in a hydroboration/(C6F5)(2)BOSiMe3 elimination sequence to give the phosphinomethyl substituted cyclopropane derivative 9, probably via a phosphiranium type intermediate. Addition of B(C6F5)(3) to compound 5 gave the stable phosphiranium/borate zwitterion 10 that was isolated and characterized by X-ray diffraction.
引用
收藏
页码：2695 / 2697
页数：3
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