Easy access to stable pentavalent uranyl complexes

被引：88

作者：

Berthet, Jean-Claude ^{[1
]}

Siffredi, Gerald ^{[1
]}

Thuery, Pierre ^{[1
]}

Ephritikhine, Michel ^{[1
]}

机构：

[1] CEA Saclay, Serv Chim Mol, DSM, DRECAM,CNRS,URA 331, F-91191 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 30期

关键词：

D O I：

10.1039/b605710a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of UO2I2(THF)(3) with 1 molar equivalent of KC5R5 ( R = H, Me) in pyridine led to the uranyl( V) compound {[UO2(Py)(5)][KI2(Py)(2)]}(infinity), which is an infinite 1D polymer in its crystalline form; the UO2X(THF)(n) (X = I, OSO2CF3) complexes were obtained by reduction of their U( VI) parents with TlC5H5 or KC5R5 in THF.

引用

页码：3184 / 3186

页数：3

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