The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar=3,5-(CF3)2C6H3)

被引：95

作者：

Fantauzzi, Simone ^{[1
,2
]}

Gallo, Emma ^{[1
,2
]}

Caselli, Alessandro ^{[1
,2
]}

Ragaini, Fabio ^{[1
,2
]}

Casati, Nicola ^{[2
,3
]}

Macchi, Piero ^{[4
]}

Cenini, Sergio ^{[1
,2
]}

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit L, I-20133 Milan, Italy

[2] CNR, ISTM, I-20133 Milan, Italy

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[4] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 26期

关键词：

TRANSITION-METAL-COMPLEXES; HYDROGEN-ATOM TRANSFER; RUTHENIUM PORPHYRINS; MANGANESE-PORPHYRINS; ARYL AZIDES; INTRAMOLECULAR AMIDATION; AZIRIDINATION; HYDROCARBONS; FUNCTIONALIZATION; ACTIVATION;

D O I：

10.1039/b903238j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.

引用

页码：3952 / 3954

页数：3

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