Imidazolylsulfonates: Electrophilic Partners in Cross-Coupling Reactions

被引：53
|
作者：
Albaneze-Walker, Jennifer [1 ]
Raju, Ravinder [1 ]
Vance, Jennifer A. [1 ]
Goodman, Andrew J. [1 ]
Reeder, Michael R. [1 ]
Liao, Jing [1 ]
Maust, Mathew T. [1 ]
Irish, Patrick A. [1 ]
Espino, Peter [1 ]
Andrews, David R. [1 ]
机构：
[1] Schering Plough Corp, Synthet Chem Chem & Phys Sci, Union, NJ 07083 USA
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 07期
关键词：
ORGANIC FUNCTIONAL-GROUPS; IMIDAZOLE-1-SULFONATES IMIDAZYLATES; ARYL TOSYLATES; SUZUKI-MIYAURA; EFFICIENT; ESTERS; ACIDS; DERIVATIVES; REACTIVITY; METAL;
D O I：
10.1021/ol802381k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aryl imidazolylsulfonates participate as electrophilic coupling partners in palladium-mediated cross-coupling reactions. The aryl imidazolylsulfonates display good stability while maintaining good reactivity in a variety of palladium-catalyzed coupling reactions. Imidazolylsulfonates are a practical and economic alternative to triflates.
引用
收藏
页码：1463 / 1466
页数：4
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