A new intercalated iron sulfide (C2H8N2)0.4Fe2S2 from solvothermal route: Synthesis, structure and tunable magnetism

被引：11
|
作者：
Wu, Dan [1 ]
Guo, Zhongnan [1 ]
Liu, Ning [2 ]
Zhou, Liang [1 ]
Mao, Yingluo [1 ]
Wan, Lin [1 ]
Sun, Fan [1 ]
Yuan, Wenxia [1 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Dept Chem, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Res & Dev Ctr Funct Crystals, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 91卷
基金：
中国国家自然科学基金;
关键词：
Intercalated FeS material; Ethanediamine; Solvothermal synthesis; Paramagnetism; Absence of superconductivity; SUPERCONDUCTING PHASES; CRYSTAL-STRUCTURE; TETRAGONAL FES; SELENIDES;
D O I：
10.1016/j.inoche.2018.03.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, a new intercalated FeS compound: (C2H8N2)(0.4)Fe2S2 was synthesized via the solvothermal route. The product is stable in air and shows the micron-sized plate shape. Structure refinement indicates that (C2H8N2)(0.4)Fe2S2 adopts the I4/m space group with the lattice constants a = 3.6906(6) and c = 20.4215(11) A. The [FeS] layer crystallizes into the anti-fluorite structure with edge-sharing tetrahedrons and the C2H8N2 molecules are inserted in between the layers. (C2H8N2)(0.4)Fe2S2 is the first intercalated FeS compound reported up to now that contains the electroneutral guest layers. This specific feature leads to the paramagnetic behavior without any magnetic transition in the measured temperature range. Furthermore, we find that the ferromagnetic interaction can also be easily induced in this compound by inserting the extra Fe in between the layers, indicating the controllable magnetism of the title compound. The absence of superconductivity in (C2H8N2)(0.4)Fe2S2 is mainly due to the external pressure on FeS layers induced by En intercalation. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：72 / 76
页数：5
相关论文
共 50 条
  • [21] Synthesis and Crystal Structure of Complex [Cd•(C7H6N2O4S)•(C10H8N4)]•2H2O
    Li, S. -X.
    Liao, B. -L.
    Yang, G. -G.
    Jiang, Y. -M.
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (06) : 926 - 929
  • [22] Thermal behaviour and optical properties of a new dimeric 1D mixed halide hybrid material [CuBrCl(C2H8N2)]
    Derbel, Marwa Abid
    Nasr, Samia
    Naili, Houcine
    Rekik, Walid
    INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 142
  • [23] Synthesis, characterization, and properties of a new thioantimonate(III), [C5N2H16]Sb8S13•H2O
    Wang, Xin
    Sheng, Tian-Lu
    Chen, Jian-Shan
    Hu, Sheng-Min
    Fu, Rui-Biao
    Wu, Xin-Tao
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 936 (1-3) : 142 - 146
  • [24] A new hydrazine-bridged thioantimonate Mn2Sb4S8(N2H4)2: Synthesis, structure, optical and magnetic properties
    Liu, Yi
    Tian, Yufeng
    Wei, FengXia
    Ping, Michael Ser Chong
    Huang, Chuanwei
    Boey, Freddy
    Kloc, Christian
    Chen, Lang
    Wu, Tom
    Zhang, Qichun
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (06) : 884 - 888
  • [25] Solvothermal Synthesis and Structure of Two 2D Tin–Selenides with Long Alkyldiamine NH2(CH2)nNH2 (n = 8, 10)
    Sheming Lu
    Yanxiong Ke
    Jianmin Li
    Shuxi Zhou
    Xintao Wu
    Wenxin Du
    Structural Chemistry, 2003, 14 : 637 - 642
  • [26] Solvothermal Synthesis and Characterization of Sheet Structure Containing Adamantane [Hg2Sn2S10]8- Anions
    Baiyin Meng-he
    Liang Feng-ying
    Xu Xiao-qing
    Ta Na
    Na Mi-la
    Bai Wu-yun
    Bao Yong-sheng
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2011, 27 (06) : 915 - 918
  • [27] Synthesis, structure and characterization of a new inorganic-organic hybrid complex (C3H5N2)2[Cd(C3H4N2)2Nb2O3F8]·2H2O
    Gang Zhu
    Xingling Xu
    Zongxun Tang
    Journal of Chemical Crystallography, 2006, 36 : 637 - 642
  • [28] Synthesis and Crystal Structure of [Cu （C8H4O2F3S） （2, 2' -bipy） ]
    WANG Dong-Mei
    XUE Bao-Yu
    YANG Rui-Na
    JIN Dou-Man(Henan Institute of Chemistry
    LUO Bao-Sheng(Wuhan University
    结构化学, 1997, (04) : 287 - 289
  • [29] New mixed ligand organotellurium(IV) compounds containing dithiocarbamates and the more flexible imidotetraphenyldithiodiphosphinates.: The crystal structures of C8H8Te(S2CNEt2)[SPPh2)2N]•H2O, C8H8Te(S2CNC5H10)[SPPh2)2N], and C8H8Te(S2CNC4H8S)[(SPPh2)2N]
    Canseco-Melchor, G
    García-Montalvo, V
    Toscano, RA
    Cea-Olivares, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (10): : 2391 - 2396
  • [30] Crystal structure and magnetism of the binuclear Gd(III) complex Gd2(C12H8N2)2(C6H5COO)6
    Niu, SY
    Jin, J
    Jin, XL
    Cong, Y
    Yang, ZZ
    CHINESE SCIENCE BULLETIN, 2000, 45 (08): : 706 - 711
12345