Chiral Framework with 20-Ring Channels Exhibiting MetalActivator- Free Photoluminescence

被引：7

作者：

Huang, Hui-Lin ^{[1
]}

Luo, Zih-Jie ^{[1
]}

Kuo, Yu-Chih ^{[1
]}

Wang, Sue-Lein ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 19期

关键词：

chiral frameworks; microporous materials; photoluminescence; renewable resources; zinc phosphite; MICROPOROUS FRAMEWORK; ACHIRAL PRECURSORS; LIGHT PHOSPHOR; CRYSTALLIZATION; GALLOPHOSPHATE; ZINCOPHOSPHATE; LUMINESCENCE; CATALYSIS; TOPOLOGY; ZEOLITE;

D O I：

10.1002/chem.201400249

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of biomass-derived sucrose has unprecedentedly induced the first chiral zinc phosphite structure with 20R channels along with a series of acentric frameworks, unveiling a facile synthesis of chiral nanoporous frameworks. The 20R-channel structures are metal-activator free but display blue-to-white photoluminescence under long UV excitation.

引用

页码：5546 / 5549

页数：4

共 27 条

[21] The ITQ-37 mesoporous chiral zeolite [J].

Sun, Junliang ;

Bonneau, Charlotte ;

Cantin, Angel ;

Corma, Avelino ;

Diaz-Cabanas, Maria J. ;

Moliner, Manuel ;

Zhang, Daliang ;

Li, Mingrun ;

Zou, Xiaodong .

NATURE, 2009, 458 (7242) :1154-U90

[22] Intrinsic yellow light phosphor:: An organic-inorganic hybrid gallium oxalatophosphate with hexameric octahedral Ga6(OH)4O26 cluster [J].

Yang, Ya-Ching ;

Wang, Sue-Lein .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (04) :1146-+

[23]

Zhang J, 2010, ANGEW CHEM, V122, P1289

[24] Homochiral crystallization of microporous framework materials from achiral precursors by chiral catalysis [J].

Zhang, Jian ;

Chen, Shumei ;

Wu, Tao ;

Feng, Pingyun ;

Bu, Xianhui .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (39) :12882-+

[25] A Tale of Three Carboxylates: Cooperative Asymmetric Crystallization of a Three-Dimensional Microporous Framework from Achiral Precursors [J].

Zhang, Jian ;

Chen, Shumei ;

Nieto, Ruben A. ;

Wu, Tao ;

Feng, Pingyun ;

Bu, Xianhui .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (07) :1267-1270

[26] Nucleotide-Catalyzed Conversion of Racemic Zeolite-Type Zincophosphate into Enantioenriched Crystals [J].

Zhang, Jian ;

Chen, Shumei ;

Bu, Xianhui .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (33) :6049-6051

[27] Integrated Molecular Chirality, Absolute Helicity, and Intrinsic Chiral Topology in Three-Dimensional Open-Framework Materials [J].

Zhang, Jian ;

Chen, Shumei ;

Zingiryan, Areg ;

Bu, Xianhui .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (51) :17246-+

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