Asymmetric synthesis of bicyclopropane derivatives

被引:19
作者
Barrett, AGM [1 ]
Doubleday, WW [1 ]
Tustin, GJ [1 ]
机构
[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523
关键词
D O I
10.1016/S0040-4020(96)00934-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Both syn- and anti-bicyclopropane derivatives have been efficiently prepared with good relative and absolute stereocontrol using reagent controlled asymmetric cyclopropanation reactions. Double Simmons-Smith cyclopropanation of 2,4-dien-1-ols stereoselectively gave the corresponding anti-bicyclopropane derivatives. Copyright (C) 1996 Elsevier Science Ltd
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页码:15325 / 15338
页数:14
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