Kinetics and mechanism of electron transfer reactions in aqueous solutions: Silver(I) catalyzed oxidation of glutamic acid by cerium(IV) in acid perchlorate medium

被引：0

作者：

Gupta, D ^{[1
]}

Bhasin, M ^{[1
]}

Deura, V ^{[1
]}

Sharma, I ^{[1
]}

Sharma, PD ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

OXIDATION COMMUNICATIONS | 1996年 / 19卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of silver(I) catalyzed oxidation of glutamic acid by cerium(IV) has bee studied in acid perchlorate medium. Both the order with respect to glutamic acid and hydrogen ion dependence are complex. The rate law corresponds to the reaction mechanism. k=(k(1)K(1)[GA(+)]+k(2)K(1)K(2)[GA(+)](2))[H+](1+K-1[GA(+)]+K1K2[GA(+)](2))(K-h+[H+]), where k is the second order rate constant.

引用

页码：242 / 250

页数：9

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