Synthesis and properties of new fullerene C60 derivatives, containing acetonide and polyol fragments

被引：5
|
作者：
Gilmutdinova, Alina A. [1 ]
Gubskaya, Valentina P. [1 ]
Fazleeva, Guzel M. [1 ]
Latypov, Shamil K. [1 ]
Zhelonkina, Tatyana A. [1 ]
Sharafutdinova, Dilara R. [1 ]
Nuretdinov, Ildus A. [1 ]
Sinyashin, Oleg G. [1 ]
机构：
[1] RAS, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
来源：
TETRAHEDRON | 2014年 / 70卷 / 35期
基金：
俄罗斯基础研究基金会;
关键词：
Hexa-methanofullerenes; Acetonide protection; Bingel-Hirsch reaction; Water-soluble polyol methanofullerenes; OCTAHEDRAL ADDITION PATTERN; EFFICIENT SYNTHESIS; BUILDING-BLOCKS; WATER; C60;
D O I：
10.1016/j.tet.2014.06.009
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New mono- and hexa-methanofullerenes containing different number of acetonide groups are synthesized and characterized. Removing the acetonide protection leads to new chromatographically pure water-soluble polyol methanofullerenes with essentially quantitative yields. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5947 / 5953
页数：7
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