Investigation on early hydration of ternary Portland cement-blast-furnace slag-metakaolin blends

被引:99
作者
Bohac, Martin [1 ]
Palou, Martin [1 ]
Novotny, Radoslav [1 ]
Masilko, Jiri [1 ]
Vsiansky, Dalibor [2 ]
Stanek, Theodor [3 ]
机构
[1] Brno Univ Technol, Fac Chem, Brno 61200, Czech Republic
[2] Masaryk Univ, Fac Sci, Dept Geol Sci, CS-61137 Brno, Czech Republic
[3] JSC, Res Inst Bldg Mat, Brno 61700, Czech Republic
关键词
Ternary system; Portland cement; Metakaolin; Blast-furnace slag; Hydration; AUTOGENOUS SHRINKAGE; POZZOLANIC ACTIVITY; SILICA FUME; FLY-ASH; CALORIMETRY; COMPOSITES; PASTES;
D O I
10.1016/j.conbuildmat.2014.04.018
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The paper investigates the hydration of ternary blends comprising Portland cement, blast-furnace slag and metakaolin. The isothermal calorimetry and "in situ" X-ray diffraction was used to evaluate the effect of metakaolin and blast-furnace slag on the early hydration of blends. XRD, DTA and SEM were used to analyze the hardened paste after 1 month of hydration. Metakaolin influences significantly the kinetics, mechanism and products of hydration at initial period of hydration causing the rapid formation of ettringite. Hemicarbonate aluminate hydrate is formed as a product of ettringite conversion due to the presence of reactive calcite in Portland cement. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:333 / 341
页数:9
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