Biosourced Nitrogen-Doped Microcellular Carbon Monoliths

被引：14

作者：

Brun, Nicolas ^{[1
]}

Osiceanu, Petre ^{[2
]}

Titirici, Magdalena M. ^{[3
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Golm, Germany

[2] Inst Phys Chem, Bucharest 060021, Romania

[3] Queen Mary Univ London, Sch Mat Sci & Engn, London E1 4NS, England

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 02期

关键词：

biomass; carbon; electrocatalysis; hydrothermal synthesis; microporous materials; BATTERY NEGATIVE ELECTRODES; DEEP EUTECTIC SOLVENTS; OXYGEN REDUCTION; CO2; CAPTURE; ELECTROCHEMICAL CAPACITORS; MACROPOROUS CARBON; ENERGY-STORAGE; PERFORMANCE; AEROGELS; NANOPARTICLES;

D O I：

10.1002/cssc.201301165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An original approach based on the hydrothermal carbonization of nitrogen-containing biomass derivatives within the continuous phase of a direct concentrated emulsion is reported for the synthesis of nitrogen-doped microcellular carbon monoliths. These biosourced foams show promising performances as intrinsic electrocatalysts in the oxygen reduction reaction. Preliminary catalytic properties of powdered versus monolithic samples are discussed and suggest interesting prospects for their introduction within electrochemical devices.

引用

页码：397 / 401

页数：5

共 55 条

[1] Generation of hierarchical meso- and macroporous carbon from mesophase pitch by spinodal decomposition using polymer templates [J].

Adelhelm, Philipp ;

Hu, Yong-Sheng ;

Chuenchom, Laemthong ;

Antonietti, Markus ;

Smarsly, Bernd M. ;

Maier, Joachim .

ADVANCED MATERIALS, 2007, 19 (22) :4012-+

[2]

[Anonymous], 2013, ANGEW CHEM INT ED, V52, P2925

[3] Combining soft matter and soft chemistry:: integrative chemistry towards designing novel and complex multiscale architectures [J].

Backov, Renal .

SOFT MATTER, 2006, 2 (06) :452-464

[4] Advanced carbon aerogels for energy applications [J].

Biener, Juergen ;

Stadermann, Michael ;

Suss, Matthew ;

Worsley, Marcus A. ;

Biener, Monika M. ;

Rose, Klint A. ;

Baumann, Theodore F. .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (03) :656-667

[5] Hydrothermal synthesis of highly porous carbon monoliths from carbohydrates and phloroglucinol [J].

Brun, Nicolas ;

Garcia-Gonzalez, Carlos A. ;

Smirnova, Irina ;

Titirici, Magdalena M. .

RSC ADVANCES, 2013, 3 (38) :17088-17096

[6] Original design of nitrogen-doped carbon aerogels from sustainable precursors: application as metal-free oxygen reduction catalysts [J].

Brun, Nicolas ;

Wohlgemuth, Stephanie A. ;

Osiceanu, Petre ;

Titirici, Magdalena M. .

GREEN CHEMISTRY, 2013, 15 (09) :2514-2524

[7] Emulsion-Templated Macroporous Carbons Synthesized By Hydrothermal Carbonization and their Application for the Enzymatic Oxidation of Glucose [J].

Brun, Nicolas ;

Edembe, Lise ;

Gounel, Sebastien ;

Mano, Nicolas ;

Titirici, Magdalena M. .

CHEMSUSCHEM, 2013, 6 (04) :701-710

[8] Hybrid foams, colloids and beyond: From design to applications [J].

Brun, Nicolas ;

Ungureanu, Simona ;

Deleuze, Herve ;

Backov, Renal .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :771-788

[9] Design of Hierarchical Porous Carbonaceous Foams from a Dual-Template Approach and Their Use as Electrochemical Capacitor and Li Ion Battery Negative Electrodes [J].

Brun, Nicolas ;

Prabaharan, Savari R. S. ;

Surcin, Christine ;

Morcrette, Mathieu ;

Deleuze, Herve ;

Birot, Marc ;

Babot, Odile ;

Achard, Marie-France ;

Backov, Renal .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (01) :1408-1421

[10] Hard Macrocellular Silica Si(HIPE) Foams Templating Micro/Macroporous Carbonaceous Monoliths: Applications as Lithium Ion Battery Negative Electrodes and Electrochemical Capacitors [J].

Brun, Nicolas ;

Prabaharan, Savari R. S. ;

Morcrette, Mathieu ;

Sanchez, Clement ;

Pecastaings, Gilles ;

Derre, Alain ;

Soum, Alain ;

Deleuze, Herve ;

Birot, Marc ;

Backov, Renal .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (19) :3136-3145

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