Coordination chemistry in and of sulfur dioxide

被引：89
作者：
Mews, R [1 ]
Lork, E [1 ]
Watson, PG [1 ]
Görtler, B [1 ]
机构：
[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany
来源：
COORDINATION CHEMISTRY REVIEWS | 2000年 / 197卷
关键词：
weakly coordinating anions; sulfur dioxide complexes; 'naked' metal cations; coordination chemistry;
D O I：
10.1016/S0010-8545(99)00191-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The review describes the syntheses of metal salts with weakly interacting anions (AlCl4-, AsF6-, SbF6-) in the poorly coordinating solvent SO2. The metal centers in the resulting complexes might be considered as almost 'naked', their unusual coordination chemistry is discussed. (C) 2000 Elsevier Science S.A. All rights reserved.
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页码：277 / 320
页数：44
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