Biodesulfurization of two Colombian coals with native microorganisms

被引:75
|
作者
Cristina Cardona, Isabel [1 ]
Antonio Marquez, Marco [1 ]
机构
[1] Univ Nacl Colombia, Appl Mineral Grp, Medellin 05001000, Colombia
关键词
Acidithiobacillus; Coal; Pyrite; Sulfur; MICROBIAL DESULFURIZATION; OXIDATION; SULFUR; THIOBACILLUS; CHEMISTRY; IRON;
D O I
10.1016/j.fuproc.2009.04.022
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A biodesulfurization process was carried out for two coals from the southwest of Colombia using a consortium of native microorganisms Acidithiobacillus ferrooxidans-like and Acidithiobacillus thiooxidans-like. Characterization techniques as X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (1717111), Scanning Electron Microscopy (SEM/EDX) and chemical analysis were used in order to establish the mineralogy of the process. The sulfur content in coals varies from 2.6% to 5.7%, and pyrite is the main sulphide present in the inorganic phase. Other minerals in the substrates include kaolinite, calcite, dolomite and quartz. An 85-95% reduction of pyritic sulfur and 31-51% of total sulfur in a period of 30 days were achieved, for a particle size of -74 mu m, 10% w/v pulp density and 30 degrees C. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1099 / 1106
页数:8
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