Electrocatalytic Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Coupled with H2 Evolution

被引：4

作者：

Meng, Ye ^{[1
]}

Li, Hu ^{[1
]}

机构：

[1] Guizhou Univ, Ctr R&D Fine Chem, Minist Educ,State Local Joint Lab Comprehens Util, Key Lab Green Pesticide & Agr Bioengn,State Key L, Guiyang 550025, Guizhou, Peoples R China

来源：

CURRENT ORGANIC CHEMISTRY | 2021年 / 25卷 / 23期

基金：

中国国家自然科学基金;

关键词：

Biomass valorization; electrocatalyst; redox mediators; bifunctional electrocatalysts; 5-hydroxymethylfurfural; 5-furandi-carboxylic acid; hydrogen evolution; HYDROGEN-PRODUCTION; WATER; CHALLENGES;

D O I：

10.2174/1385272825666210927101643

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simultaneous electrocatalytic conversion of biomass into high-value products and electrolysis of water for hydrogen are promising strategies to relieve the fossil energy crisis. Herein, we overview the recent advances and perspectives in the electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) and water reduction to synchronously produce value-added 2,5-furandicarboxylic acid (FDCA) and hydrogen fuel. Two strategies of bifunctional electrocatalysts and redox mediators are discussed. Oxidation of HME to FDCA was found to be more thermodynamically and kinetically favorable than the Oxygen Evolution Reaction (OER). Moreover, the opportunities and challenges brought by them are presented.

引用

页码：2810 / 2814

页数：5

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