Synergistic effect of coal blends on thermoplasticity evaluated using a temperature-variable dynamic viscoelastic measurement

To maximize the conversion of low-quality coal into good coke, we investigated the thermoplasticity of various binary blends of caking coals with slightly or noncaking coals using a dynamic viscoelastic technique with a temperature-variable rheometer. Coal blend samples were prepared by mixing two coals (1:1 by weight), which were heated from room temperature to 600 degrees C at a rate of 3-80 degrees C/min. At the slow rate of 3 degrees C/min, the blends had a tan delta that was generally lower than the calculated value, showing that a negative interaction caused a loss of thermoplasticity. In contrast, at the rapid heating rate of 80 degrees C/min, the tan delta of some blends was higher than the calculated value, indicating a positive interaction that enhanced the thermoplasticity. With rapid heating, the thermoplasticity of each coal itself increased, and their thermoplastic temperature ranges widened with rapid heating. Therefore, rapid heating was effective at converting these coal blends into good cokes. Moreover, even with slow heating, when a combination of coals (Gregory:Enshu, 1:1) showing some thermoplasticity in nearly the same temperature range was blended, a desirable synergistic effect of the blend was obtained. This suggests that blending coal with an overlapping thermoplastic temperature range is important for the synergistic effect, regardless of the heating rate.