Terpenes to Ionic Liquids: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids

被引：15
|
作者：
Nageshwar, D. [2 ]
Rao, D. Muralimohan [3 ]
Acharyulu, Palle V. R. [1 ]
机构：
[1] Haritha Labs, Hyderabad 500049, Andhra Pradesh, India
[2] Dr Reddys Labs, Custom Pharmaceut Serv, Technol Dev Ctr, Hyderabad, Andhra Pradesh, India
[3] Jawaharlal Nehru Technol Univ, Coll Engn, Kakinada, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 18期
关键词：
Citronellal; ionic liquids; quaternary ammonium salts; reductive amination; terpenes; CATALYTIC BECKMANN REARRANGEMENT; DIELS-ALDER REACTIONS; HECK REACTION; SOLVENTS;
D O I：
10.1080/00397910902768226
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of new chiral ionic liquids have been prepared and characterized starting from a simple, economical, and commercially available monoterpene, citronellal. The aldehyde functionality in citronellal is converted into a Schiff base using an amine, followed by reduction with Raney nickel to give the desired quaternary amine. Most of the ionic liquids generated using this procedure are found to be liquids at room temperature.
引用
收藏
页码：3357 / 3368
页数：12
相关论文
共 50 条
  • [41] Synthesis and characterization of novel chiral ionic liquids and investigation of their enantiomeric recognition properties
    Bwambok, David K.
    Marwani, Hadi M.
    Fernand, Vivian E.
    Fakayode, Sayo O.
    Lowry, Mark
    Negulescu, Ioan
    Strongin, Robert M.
    Warner, Isiah M.
    CHIRALITY, 2008, 20 (02) : 151 - 158
  • [42] Synthesis and characterization of diimidazole-based hexafluorophosphate ionic liquids
    Huang, Ting
    Zhao, Wen
    Zhang, Xiaohua
    Nie, Xuliang
    Chen, Jing
    Xiong, Wanming
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 320
  • [43] Bicyclic imidazolium-based ionic liquids: synthesis and characterization
    Kan, Huang-Chuan
    Tseng, Ming-Chung
    Chu, Yen-Ho
    TETRAHEDRON, 2007, 63 (07) : 1644 - 1653
  • [44] Synthesis and Characterization of 5-Cyanotetrazolide-Based Ionic Liquids
    Bergholz, Timm
    Oelkers, Benjamin
    Huber, Benedikt
    Roling, Bernhard
    Sundermeyer, Joerg
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (06) : 2613 - 2620
  • [45] Chiral Discrimination by Ionic Liquids: Impact of Ionic Solutes
    Brown, Christopher J.
    Hopkins, Todd A.
    CHIRALITY, 2015, 27 (04) : 320 - 325
  • [46] Synthesis and Characterization of Novel Isonicotinate-based Ionic Liquids
    Miao, Chengping
    Zong, Qianshou
    Xiang, Ziwei
    Wu, Jianyi
    FUNDAMENTAL OF CHEMICAL ENGINEERING, PTS 1-3, 2011, 233-235 : 1266 - +
  • [47] Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids
    Fei, Teng
    Cai, Huiwu
    Zhang, Yanqiang
    Liu, Long
    Zhang, Suojiang
    JOURNAL OF ENERGETIC MATERIALS, 2016, 34 (02) : 138 - 151
  • [48] Synthesis and characterization of fluorinated phosphonium ionic liquids
    Tindale, Jocelyn J.
    Na, Chris
    Jennings, Michael C.
    Ragogna, Paul J.
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2007, 85 (10): : 660 - 667
  • [49] Synthesis, characterization, and catalytic activity of ionic liquids based on biosources
    Moriel, P.
    Garcia-Suarez, E. J.
    Martinez, M.
    Garcia, A. B.
    Montes-Moran, M. A.
    Calvino-Casilda, V.
    Banares, M. A.
    TETRAHEDRON LETTERS, 2010, 51 (37) : 4877 - 4881
  • [50] Synthesis and Characterization of Imidazolium Perrhenate Ionic Liquids
    Yue, Shuang
    Fang, Da-Wei
    Li, Jun
    Zang, Shu-Liang
    Zhou, Ming-Dong
    Zhang, Bo
    Markovits, Iulius I. E.
    Cokoja, Mirza
    Kuehn, Fritz E.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (5-6): : 598 - 604
12345