Terpenes to Ionic Liquids: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids

被引：15
|
作者：
Nageshwar, D. [2 ]
Rao, D. Muralimohan [3 ]
Acharyulu, Palle V. R. [1 ]
机构：
[1] Haritha Labs, Hyderabad 500049, Andhra Pradesh, India
[2] Dr Reddys Labs, Custom Pharmaceut Serv, Technol Dev Ctr, Hyderabad, Andhra Pradesh, India
[3] Jawaharlal Nehru Technol Univ, Coll Engn, Kakinada, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 18期
关键词：
Citronellal; ionic liquids; quaternary ammonium salts; reductive amination; terpenes; CATALYTIC BECKMANN REARRANGEMENT; DIELS-ALDER REACTIONS; HECK REACTION; SOLVENTS;
D O I：
10.1080/00397910902768226
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of new chiral ionic liquids have been prepared and characterized starting from a simple, economical, and commercially available monoterpene, citronellal. The aldehyde functionality in citronellal is converted into a Schiff base using an amine, followed by reduction with Raney nickel to give the desired quaternary amine. Most of the ionic liquids generated using this procedure are found to be liquids at room temperature.
引用
收藏
页码：3357 / 3368
页数：12
相关论文
共 50 条
  • [31] Organocatalysis with Chiral Ionic Liquids
    Zalewska, Karolina
    Branco, Luis C.
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2014, 11 (02) : 141 - 153
  • [32] Solvent-free synthesis of protic ionic liquids. Synthesis, characterization and computational studies of triazolium based ionic liquids
    Morais, Eduardo Maurina
    Abdurrokhman, Iqbaal
    Martinelli, Anna
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 360
  • [33] Recent advances in the synthesis and application of chiral ionic liquids
    Winkel, Andreas
    Reddy, Peddiahgari Vasu Govardhana
    Wilhelm, Rene
    SYNTHESIS-STUTTGART, 2008, (07): : 999 - 1016
  • [34] Chiral ionic liquids: Synthesis, properties, and enantiomeric recognition
    Yu, Shaofang
    Lindeman, Sergey
    Tran, Chieu D.
    JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (07): : 2576 - 2591
  • [35] Chiral Ionic Liquids from Carbohydrates: Synthesis and Properties
    Pereira, M. Manuela A.
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2012, 9 (03) : 243 - 260
  • [36] Facile synthesis of ionic liquids possessing chiral carboxylates
    Allen, Christine R.
    Richard, Paulina L.
    Ward, Antony J.
    van de Water, Leon G. A.
    Masters, Anthony F.
    Maschmeyer, Thomas
    TETRAHEDRON LETTERS, 2006, 47 (41) : 7367 - 7370
  • [37] Synthesis of Chiral Ionic Liquids from Natural Monosaccharides
    Ghirardello, Mattia
    Costantini, Maira
    Vecchi, Alessandra
    Pacifico, Salvatore
    Pazzi, Daniele
    Castiglione, Franca
    Mele, Andrea
    Marra, Alberto
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 2022 (21)
  • [38] Design and synthesis of novel chiral spiro ionic liquids
    Patil, ML
    Rao, CVL
    Yonezawa, K
    Takizawa, S
    Onitsuka, K
    Sasai, H
    ORGANIC LETTERS, 2006, 8 (02) : 227 - 230
  • [39] Synthesis in ionic liquids
    Laali, Kenneth K.
    CURRENT ORGANIC SYNTHESIS, 2007, 4 (04) : 352 - 353
  • [40] Synthesis, characterization, and application of chiral ionic liquids and their polymers in micellar electrokinetic chromatography
    Rizvi, Syed Asad Ali
    Shamsi, Shahab A.
    ANALYTICAL CHEMISTRY, 2006, 78 (19) : 7061 - 7069
12345