Terpenes to Ionic Liquids: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids

被引：15
|
作者：
Nageshwar, D. [2 ]
Rao, D. Muralimohan [3 ]
Acharyulu, Palle V. R. [1 ]
机构：
[1] Haritha Labs, Hyderabad 500049, Andhra Pradesh, India
[2] Dr Reddys Labs, Custom Pharmaceut Serv, Technol Dev Ctr, Hyderabad, Andhra Pradesh, India
[3] Jawaharlal Nehru Technol Univ, Coll Engn, Kakinada, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 18期
关键词：
Citronellal; ionic liquids; quaternary ammonium salts; reductive amination; terpenes; CATALYTIC BECKMANN REARRANGEMENT; DIELS-ALDER REACTIONS; HECK REACTION; SOLVENTS;
D O I：
10.1080/00397910902768226
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of new chiral ionic liquids have been prepared and characterized starting from a simple, economical, and commercially available monoterpene, citronellal. The aldehyde functionality in citronellal is converted into a Schiff base using an amine, followed by reduction with Raney nickel to give the desired quaternary amine. Most of the ionic liquids generated using this procedure are found to be liquids at room temperature.
引用
收藏
页码：3357 / 3368
页数：12
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