Efficient synthesis of functionalized organozinc compounds by the direct insertion of zinc into organic iodides and bromides

被引：390

作者：

Krasovskiy, Arkady ^{[1
]}

Malakhov, Vladimir ^{[1
]}

Gavryushin, Andrei ^{[1
]}

Knochel, Paul ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 36期

关键词：

coupling; homogeneous catalysis; insertion; organozinc compounds; zinc;

D O I：

10.1002/anie.200601450

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Insider dealing: A wide range of poly-functional (hetero)aromatic and aliphatic zinc reagents can be easily prepared in THF. The compounds are formed by a Zn insertion reaction mediated by the addition of LiCl (see scheme; All = allyl). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6040 / 6044

页数：5

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