Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

被引：17
作者：
Blug, Matthias [1 ]
Gruenstein, Dan [1 ]
Alcaraz, Gilles [2 ,3 ]
Sabo-Etienne, Sylviane [2 ,3 ]
Le Goff, Xavier-Frederic [1 ]
Le Floch, Pascal [1 ]
Mezailles, Nicolas [1 ]
机构：
[1] Ecole Polytech, Lab Heteroelements & Coordinat, CNRS, DCPH,UMR 7653, F-91128 Palaiseau, France
[2] CNRS, LCC, F-31077 Toulouse, France
[3] Univ Toulouse, UPS, INPT, F-31077 Toulouse, France
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 29期
关键词：
TRANSITION-METAL-COMPLEXES; CATALYZED DEHYDROGENATION; AMMONIA-BORANE; CRYSTAL-STRUCTURE; STABILIZED CARBANION; RUTHENIUM COMPLEXES; SIGMA-COMPLEXES; H ACTIVATION; CARBENE; AMINE;
D O I：
10.1039/b907813d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The stoichiometric reaction of [Rh(COD)Cl](2) with the anion resulting from the deprotonation of dppm(BH3)(2) yielded a new alkyl Rh(I) complex; the coordination modes of the BH3 groups are discussed on the basis of X-ray data, variable temperature multinuclear NMR experiments and DFT studies.
引用
收藏
页码：4432 / 4434
页数：3
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