Colossal dielectric response in all-ceramic percolative composite 0.65Pb(Mg1/3Nb2/3)O3-0.35PbTiO3-Pb2Ru2O6.5

被引:6
作者
Bobnar, V. [1 ]
Hrovat, M. [1 ]
Holc, J. [1 ]
Filipic, C. [1 ]
Levstik, A. [1 ]
Kosec, M. [1 ]
机构
[1] Jozef Stefan Inst, SI-1001 Ljubljana, Slovenia
关键词
composite materials; electrical conductivity; ferroelectric ceramics; lead compounds; percolation; permittivity; CRITICAL-BEHAVIOR; CONSTANT; THRESHOLD; CONDUCTIVITY; FERROELECTRICS; SYSTEM; TRANSPORT; CRYSTALS; METAL;
D O I
10.1063/1.3075905
中图分类号
O59 [应用物理学];
学科分类号
摘要
An exceptionally high dielectric constant was obtained by making use of the conductive percolative phenomenon in all-ceramic composite, comprising of Pb2Ru2O6.5 with high electrical conductivity denoted as the conductive phase and ferroelectric 0.65Pb(Mg1/3Nb2/3)O-3-0.35PbTiO(3) (PMN-PT) perovskite systems. Structural analysis revealed a uniform distribution of conductive ceramic grains within the PMN-PT matrix. Consequently, the dielectric response in the PMN-PT-Pb2Ru2O6.5 composite follows the predictions of the percolation theory. Thus, close to the percolation point exceptionally high values of the dielectric constant were obtained-values higher than 10(5) were detected at room temperature at 1 kHz. Fit of the data, obtained for samples of different compositions, revealed critical exponent and percolation point, which reasonably agree with the theoretically predicted values.
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页数:5
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共 32 条
[1]   CRITICAL BEHAVIOR OF COMPLEX DIELECTRIC-CONSTANT NEAR PERCOLATION THRESHOLD OF A HETEROGENEOUS MATERIAL [J].
BERGMAN, DJ ;
IMRY, Y .
PHYSICAL REVIEW LETTERS, 1977, 39 (19) :1222-1225
[2]   Giant dielectric response in Pb(Zr, Ti)O3-Pb2Ru2O6.5 all-ceramic percolative composite [J].
Bobnar, Vid ;
Hrovat, Marko ;
Holc, Janez ;
Kosec, Marija .
APPLIED PHYSICS LETTERS, 2008, 92 (18)
[3]   ac and dc percolative conductivity of magnetite-cellulose acetate composites [J].
Chiteme, C. ;
McLachlan, D. S. ;
Sauti, G. .
PHYSICAL REVIEW B, 2007, 75 (09)
[4]   Dielectric properties of (PMN)(1-x)(PT)x single crystals for various electrical and thermal histories [J].
Colla, EV ;
Yushin, NK ;
Viehland, D .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (06) :3298-3304
[5]   Novel ferroelectric polymer composites with high dielectric constants [J].
Dang, ZM ;
Lin, YH ;
Nan, CW .
ADVANCED MATERIALS, 2003, 15 (19) :1625-+
[6]   Effect of interparticle distance and interfacial area on the properties of insulator-conductor composites [J].
Deepa, K. S. ;
Sebastian, M. T. ;
James, J. .
APPLIED PHYSICS LETTERS, 2007, 91 (20)
[7]   CRITICAL BEHAVIOR OF CONDUCTIVITY AND DIELECTRIC-CONSTANT NEAR METAL-NON-METAL TRANSITION THRESHOLD [J].
EFROS, AL ;
SHKLOVSKII, BI .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1976, 76 (02) :475-485
[8]   TRANSPORT-PROPERTIES OF CONTINUUM-SYSTEMS NEAR THE PERCOLATION-THRESHOLD [J].
FENG, SC ;
HALPERIN, BI ;
SEN, PN .
PHYSICAL REVIEW B, 1987, 35 (01) :197-214
[9]   CRITICAL-BEHAVIOR OF THE DIELECTRIC-CONSTANT OF A RANDOM COMPOSITE NEAR THE PERCOLATION-THRESHOLD [J].
GRANNAN, DM ;
GARLAND, JC ;
TANNER, DB .
PHYSICAL REVIEW LETTERS, 1981, 46 (05) :375-378
[10]   Enhanced dielectric and electromechanical responses in high dielectric constant all-polymer percolative composites [J].
Huang, C ;
Zhang, QM .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (05) :501-506