H2 line-mixing coefficients in the ν2 and ν4 bands of PH3 at low temperature

被引:2
作者
Salem, Jamel [1 ]
Blanquet, Ghislain [2 ]
Lepere, Muriel [2 ]
Aroui, Hassen [1 ]
机构
[1] Univ Tunis, Ecole Natl Super Ingn Tunis, Lab Dynam Mol & Mat Photon, 5 Ave Taha Hussein, Tunis 1008, Tunisia
[2] Univ Namur, Res Ctr Phys Matter & Radiat, Lab Lasers & Spectroscopies, 61 Rue Bruxelles, B-5000 Namur, Belgium
关键词
V(4) BANDS; N-2-BROADENING COEFFICIENTS; H-2-BROADENING COEFFICIENTS; INFRARED SPECTRUM; PHOSPHINE; HYDROGEN; V(2); NH3; ABSORPTION; PARAMETERS;
D O I
10.1016/j.jqsrt.2016.01.010
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Using a tunable diode-laser spectrometer adapted with a low temperature cell, we have measured the H-2 line-mixing coefficients for 21 lines in the R-Q branch of the nu(2) band and in the RP and RP branches of the nu(4) band of phosphine (PH3) at low temperature. These coefficients were determined using a multi-pressure fitting procedure that accounts for the apparatus function, the Doppler and the collisional effects. These lines with J values ranging from 2 to 11 and K from 0 to 9 are located in the spectral range from 1016 to 1093 cm(-1). The variations of these parameters with the temperature, and the rovibrational quantum numbers are discussed. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:34 / 39
页数:6
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