A Negatively Charged Hydrophobic Hemi-micelle of Fe3O4/Ag MNP Role Towards SERS, Photocatalysis and Bactericidal

被引:23
作者
Aarthi, A. [1 ]
Umadevi, M. [1 ]
Parimaladevi, R. [1 ]
Sathe, G. V. [2 ]
Arumugam, S. [3 ]
Sivaprakash, P. [3 ]
机构
[1] Mother Teresa Womens Univ, Dept Phys, Kodaikanal 624102, India
[2] UGC DAE Consortium Sci Res, Indore, India
[3] Bharathidasan Univ, Ctr High Pressure Res, Trichy 620024, India
关键词
Fe3O4 Ag MNP; R6G; SERS; Photocatalysis; Antibacterial activity; MAGNETIC NANOPARTICLES; ANTIBACTERIAL ACTIVITY; SILVER NANOPARTICLES; CHEMICAL-REDUCTION; RAMAN-SPECTROSCOPY; LANDFILL LEACHATE;
D O I
10.1007/s10904-020-01802-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Surface enhanced Raman scattering (SERS), photocatalytic and antibacterial activities of Fe3O4/Ag magnetic nano particle (MNP) is reported in this work. A synthesized Fe3O4/Ag MNP is characterized with UV-visible, vibrational spectral studies (FT-IR), X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and transmission electron microscopy (TEM). VSM reports Fe3O4/Ag MNP posses good magnetic response and attribute as a SERS substrate. SERS property of Fe3O4/Ag MNP has studied with 10(-8) M, 10(-10) M and 10(-12) M concentrations of R6G. Photocatalytic efficiency was calculated with both R6G and environmentally ignored real (leachate) sample. The degradation takes place with rate constant (-)0.012 min(-1). Moreover, degradation efficiency of Ag NPs has improved with Fe3O4 NPs. Also, as synthesized substrate shows an antibacterial activity against gram negative and gram positive bacteria with an inhibition zone of 5-8 mm. Both photonic and antibacterial properties make this material as promise for potential applications in environmental pollution, human medicine and contaminated drinking water. Graphic
引用
收藏
页码:1469 / 1479
页数:11
相关论文
共 26 条
[1]   Detection and degradation of leachate in groundwater using ag modified Fe3O4 nanoparticle as sensor [J].
Aarthi, A. ;
Umadevi, M. ;
Parimaladevi, R. ;
Sathe, G. V. .
JOURNAL OF MOLECULAR LIQUIDS, 2018, 252 :97-102
[2]   Simultaneous preparation of Ag/Fe3O4 core-shell nanocomposites with enhanced magnetic moment and strong antibacterial and catalytic properties [J].
Amarjargal, Altangerel ;
Tijing, Leonard D. ;
Im, Ik-Tae ;
Kim, Cheol Sang .
CHEMICAL ENGINEERING JOURNAL, 2013, 226 :243-254
[3]   Silver-coated magnetite-carbon core-shell microspheres as substrate-enhanced SERS probes for detection of trace persistent organic pollutants [J].
An, Qiao ;
Zhang, Peng ;
Li, Jun-Mei ;
Ma, Wan-Fu ;
Guo, Jia ;
Hu, Jun ;
Wang, Chang-Chun .
NANOSCALE, 2012, 4 (16) :5210-5216
[4]   Structural studies of viruses by Raman spectroscopy part LXXI -: Tyrosine Raman signatures of the filamentous virus Ff are diagnostic of non-hydrogen-bonded phenoxyls:: Demonstration by Raman and infrared spectroscopy of p-cresol vapor [J].
Arp, Z ;
Autrey, D ;
Laane, J ;
Overman, SA ;
Thomas, GJ .
BIOCHEMISTRY, 2001, 40 (08) :2522-2529
[5]   Magnetic Iron Oxide Nanoparticles: Reproducible Tuning of the Size and Nanosized-Dependent Composition, Defects, and Spin Canting [J].
Baaziz, Walid ;
Pichon, Benoit P. ;
Fleutot, Solenne ;
Liu, Yu ;
Lefevre, Christophe ;
Greneche, Jean-Marc ;
Toumi, Mohamed ;
Mhiri, Tahar ;
Begin-Colin, Sylvie .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (07) :3795-3810
[6]   Enhanced antibacterial activity of bimetallic gold-silver core-shell nanoparticles at low silver concentration [J].
Banerjee, Madhuchanda ;
Sharma, Shilpa ;
Chattopadhyay, Arun ;
Ghosh, Siddhartha Sankar .
NANOSCALE, 2011, 3 (12) :5120-5125
[7]   Functional Fe3O4/TiO2 core/shell magnetic nanoparticles as photokilling agents for pathogenic bacteria [J].
Chen, Wei-Jen ;
Tsai, Pei-Jane ;
Chen, Yu-Chie .
SMALL, 2008, 4 (04) :485-491
[8]   Understanding the Effect of Adsorption Geometry over Substrate Selectivity in the Surface-Enhanced Raman Scattering Spectra of Simazine and Atrazine [J].
Costa, Jean C. S. ;
Ando, Romulo A. ;
Camargo, Pedro H. C. ;
Corio, Paola .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (10) :4184-4190
[9]   Preparation of Thiol Modified Fe3O4@Ag Magnetic SERS Probe for PAHs Detection and Identification [J].
Du, Jingjing ;
Jing, Chuanyong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (36) :17829-17835
[10]   Functionalization of Ag nanoparticles with the bis-acridinium lucigenin as a chemical assembler in the detection of persistent organic pollutants by surface-enhanced Raman scattering [J].
Guerrini, L. ;
Aliaga, A. E. ;
Carcamo, J. ;
Gomez-Jeria, J. S. ;
Sanchez-Cortes, S. ;
Campos-Vallette, M. M. ;
Garcia-Ramos, J. V. .
ANALYTICA CHIMICA ACTA, 2008, 624 (02) :286-293