Schottky Barrier Height at TiN/HfO2 Interface of TiN/HfO2/SiO2/Si Structure

被引:1
作者
Han, K. [1 ]
Wang, X. L. [1 ]
Wang, W. W. [1 ]
Zhang, J. [2 ]
Xiang, J. J. [1 ]
Yang, H. [1 ]
Zhao, C. [1 ]
Chen, D. P. [1 ]
Ye, T. C. [1 ]
机构
[1] Chinese Acad Sci, Inst Microelect, Key Lab Microelect Devices & Integrated Technol, Beijing 100029, Peoples R China
[2] North China Univ Technol, Microelectron Dept, Beijing 100041, Peoples R China
来源
DIELECTRIC MATERIALS AND METALS FOR NANOELECTRONICS AND PHOTONICS 10 | 2012年 / 50卷 / 04期
关键词
OXIDES; METAL;
D O I
10.1149/05004.0299ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Band alignment of TiN/HfO2 interface of TiN/HfO2/SiO2/Si stack is investigated by x-ray photoelectron spectroscopy (XPS). The p-type Schottky barrier height (p-SBH) is found to increase with thicker HfO2 thickness. Since considering only the metal/dielectric interface cannot explain this phenomenon, band alignment of TiN/HfO2 interface of TiN/HfO2/SiO2/Si stack is demonstrated based on band alignment of entire gate stack. Dependence of p-SBH on HfO2 thickness is interpreted and contributed to fixed charges in gate stack, interfacial gap state charges at HfO2/SiO2 interface, and space charges in Si substrate. Electrical measurements of capacitor structures further support XPS results and corresponding explanation.
引用
收藏
页码:299 / 304
页数:6
相关论文
共 12 条
[1]   Internal photoemission at interfaces of high-κ insulators with semiconductors and metals [J].
Afanas'ev, V. V. ;
Stesmans, A. .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (08)
[2]   Investigation of HfO2 high-k dielectrics electronic structure on SiO2/Si substrate by x-ray photoelectron spectroscopy [J].
Duan, T. L. ;
Yu, H. Y. ;
Wu, L. ;
Wang, Z. R. ;
Foo, Y. L. ;
Pan, J. S. .
APPLIED PHYSICS LETTERS, 2011, 99 (01)
[3]   p-type Fermi level pinning at a Si:Al2O3 model interface [J].
Fonseca, L. R. C. ;
Liu, D. ;
Robertson, J. .
APPLIED PHYSICS LETTERS, 2008, 93 (12)
[4]  
Hobbs C., 2003, 2003 Symposium on VLSI Technology. Digest of Technical Papers (IEEE Cat. No.03CH37407), P9, DOI 10.1109/VLSIT.2003.1221060
[5]   Surface passivation and electronic structure characterization of PbTiO3 thin films and Pt/PbTiO3 interfaces -: art. no. 104110 [J].
Kurasawa, M ;
McIntyre, PC .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (10)
[6]  
Migita S., 2010, IEDM, P269
[8]   Band offsets of wide-band-gap oxides and implications for future electronic devices [J].
Robertson, J .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2000, 18 (03) :1785-1791
[9]   THEORY OF SEMICONDUCTOR HETEROJUNCTIONS - THE ROLE OF QUANTUM DIPOLES [J].
TERSOFF, J .
PHYSICAL REVIEW B, 1984, 30 (08) :4874-4877
[10]   Physical origin of dipole formation at high-k/SiO2 interface in metal-oxide-semiconductor device with high-k/metal gate structure [J].
Wang, Xiaolei ;
Han, Kai ;
Wang, Wenwu ;
Chen, Shijie ;
Ma, Xueli ;
Chen, Dapeng ;
Zhang, Jing ;
Du, Jun ;
Xiong, Yuhua ;
Huang, Anping .
APPLIED PHYSICS LETTERS, 2010, 96 (15)