Synthesis, Crystal Structure and Luminescence Property of A Cd(II) Complex with Benzimidazole-5-carboxylic Acid

被引：0

作者：

Tang Zhi-Wei ^{[1
]}

Fu Jun-Dan ^{[1
]}

Feng Xia ^{[1
]}

Chen Ling ^{[1
]}

Wen Yi-Hang ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Zhejiang Key Lab React Chem Solid Surfaces, Inst Phys Chem, Jinhua 321004, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 08期

关键词：

Cd(II) complex; benzimidazole-5-carboxylic acid; hydrothermally synthesis; luminescence property; SUPRAMOLECULAR ISOMERISM; COORDINATION POLYMERS; FLUORESCENT EMISSION; ORGANIC FRAMEWORKS;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Cd(II) complex, [Cd(L)(2)(H2O)](n) (1), based on benzimidazole-5-carboxylic acid (HL) ligand has been hydrothermally synthesized. The Cd(II) atoms have a distorted octahedron coordination geometry. Each L ligand links two Cd(II) atoms and each CD(II) atom attaches to four L ligands to form a two-dimensional (2D) layer structure along be plane, which consists of regular parallelograms, then yield a three-dimensional (3D) supramolecular network by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds. The TGA and luminescence property in solid state of complex 1 have been further studied and discussed in this paper. CCDC: 722775.

引用

页码：1402 / 1407

页数：6

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