Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst

被引：40

作者：

Wei, Duo ^{[1
]}

Roisnel, Thierry ^{[1
]}

Darcel, Christophe ^{[1
]}

Clot, Eric ^{[2
]}

Sortais, Jean-Baptiste ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Sci Chim Rennes, CNRS, UMR 6226, 263 Ave Gen Leclerc, F-35046 Rennes, France

[2] Univ Montpellier, Inst Charles Gerhardt, UMR CNRS UM ENSCM 5253, Pl Eugene Bataillon,Cc 1501, F-34095 Montpellier 5, France

来源：

CHEMCATCHEM | 2017年 / 9卷 / 01期

关键词：

METAL FRAGMENTS M; GAMMA-VALEROLACTONE; CATALYTIC CONVERSION; PINCER COMPLEXES; STEREOSELECTIVE HYDROGENATION; ALKENE HYDROGENATIONS; RUTHENIUM COMPLEXES; NITROSYL COMPLEXES; MILD CONDITIONS; PNP;

D O I：

10.1002/cctc.201601141

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first efficient and general rhenium-catalyzed hydrogenation of carbonyl derivatives was developed. The key to the success of the reaction was the use of a well-defined rhenium complex bearing a tridentate diphosphinoamino ligand as the catalyst (0.5 mol%) at 70 degrees C in the presence of H-2 (30 bar). The mechanism of the reaction was investigated by DFT(PBE0-D3) calculations.

引用

页码：80 / 83

页数：4

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