Dinitrogen Fixation by Transition Metal Hydride Complexes

被引:35
作者
Shima, Takanori [1 ,2 ]
Hou, Zhaomin [1 ,2 ]
机构
[1] RIKEN, Organometall Chem Lab, 2-1 Hirosawa, Wako, Saitama 3510198, Japan
[2] RIKEN, RIKEN Ctr Sustainable Resource Sci, 2-1 Hirosawa, Wako, Saitama 3510198, Japan
来源
NITROGEN FIXATION | 2017年 / 60卷
关键词
Dinitrogen cleavage; Hydride; Hydrogenation; Multimetallic; Nitride; RADIATION-CATALYTIC REDUCTION; ON-BOUND DINITROGEN; MOLECULAR NITROGEN; COORDINATED DINITROGEN; SIDE-ON; AMMONIA-SYNTHESIS; MOLYBDENUM COMPLEXES; BOND-CLEAVAGE; END-ON; N-2;
D O I
10.1007/3418_2016_3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This chapter describes the activation of dinitrogen by various transition metal hydride complexes. A number of mononuclear transition metal hydride complexes can incorporate dinitrogen, but they are usually difficult to induce N-N bond cleavage. In contrast, multimetallic hydride complexes can split and hydrogenate dinitrogen through cooperation of the multiple metal hydrides. In this transformation, the hydride ligands serve as the source of both electron and proton, thus enabling the cleavage and hydrogenation of dinitrogen without extra reducing agents and proton sources. Generally, the reactivity of the metal hydride complexes is significantly influenced by their composition (nuclearity) and metal/ligand combination.
引用
收藏
页码:23 / 43
页数:21
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