Switchable Dielectric Materials Based on 2-Methylimidazole

被引：7
作者：
Chen Li-Zhuang [1 ]
Sun Jun [1 ]
Ji Qin [1 ]
Pan Qi-Jian [1 ]
Huang Yao [2 ]
机构：
[1] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212003, Peoples R China
[2] Yunnan Open Univ, Sch Chem Engn, Kunming 650223, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 02期
基金：
中国国家自然科学基金;
关键词：
crystal structure; solution method; luminescent property; reversible dielectric; FERROELASTIC PHASE-TRANSITION; COORDINATION POLYMERS; LUMINESCENT; IMIDAZOLE; MOLECULES; MOTION;
D O I：
10.14102/j.cnki.0254-5861.2011-1252
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel coordination polymers with molecular structures (2MI)(+)[Zn(2MI)Cl-3](1) and (2MI)+NO3- (2) based on ligand 2-methylimidazole (2MI) were synthesized under solution method. Compound 1 crystallizes in the monoclinic system, space group Cc with a = 7.489(2), b = 13.448(4), c = 13.983(4) angstrom, beta = 98.402(2)degrees, Z = 4 and V = 102.246(2) angstrom(3). Compound 2 crystallizes in the orthorhombic system, space group pnma with a = 14.296(3), b = 6.3180(12), c = 7.3862(13) angstrom, beta = 90 degrees, Z = 4 and V = 667.1(2) angstrom(3). Dielectric measurements show compounds 1 and 2 have reversible dielectric anomalous behaviors with variation frequencies at different temperature.
引用
收藏
页码：329 / +
页数：12
相关论文
共 50 条
  • [21] Heat capacities and thermodynamic functions of the ZIF organic linkers imidazole, 2-methylimidazole, and 2-ethylimidazole
    Calvin, Jason J.
    Rosen, Peter F.
    Smith, Stacey J.
    Woodfield, Brian F.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 132 : 129 - 141
  • [22] ANTIBACTERIAL PROPERTIES OF HEMIAMINAL OF 2-METHYLIMIDAZOLE AND ITS INTERACTION WITH IONIC AND NON-IONIC SURFACTANTS
    Aonofriesei, Florin
    Sampaio, Ana Cristina
    Stanciu, Gabriela
    Lupsor, Simona
    FARMACIA, 2021, 69 (02) : 299 - 306
  • [23] Interaction Between 2-Methylimidazole and 1-Butanol/1-Octanol: Thermophysical and Computational Studies
    Pradhan, Sanghamitra
    Behera, Santosh Kumar
    Samal, Sangram Keshari
    Panda, Itishree
    Sahu, Pratyush Kumar
    Priyadarshini, Swayamprabha
    CHEMISTRYSELECT, 2023, 8 (13):
  • [24] 2-Methylimidazole assisted synthesis of nanocrystalline shell reinforced PPy hydrogel with high mechanical and electrochemical performance
    Tang, Shunhe
    Yu, Chuying
    Liu, Xinxin
    Fu, Danchen
    Liao, Wentao
    Xu, Feng
    Zhong, Wenbin
    CHEMICAL ENGINEERING JOURNAL, 2022, 430
  • [25] Study of the Mechanism of the Alkylation of 2-Methylimidazole with 1,1,3,3-Tetraiodopropane-2-one by MALDI Mass Spectrometry
    Klyba, L. V.
    Sanzheeva, E. R.
    Dorofeev, I. A.
    Shagun, V. A.
    Fedorova, G. A.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 60 (11) : 2147 - 2156
  • [26] Neutral and ionic Co(<sc>ii</sc>) metal-organic frameworks with 2-methylimidazole and trimesate: design and evaluation for molecule encapsulation and slow release
    Garcia, Jose de Jesus Velazquez
    Valladares, Luis de los Santos
    Barnes, Crispin H. W.
    Koenig, Sandra
    Froeba, Michael
    Baran, Volodymyr
    Knjo, Bassima
    Khademhir, Faegheh
    Ekineken, Aliyenur
    Hain, Fabienne
    Carstensen, Evke
    Spillner, Tom
    Herrera, Lina Asprilla
    Lukaszczyk, Weronika
    Techert, Simone
    DALTON TRANSACTIONS, 2025, 54 (11)
  • [27] Mononuclear copper (II) salicylate complexes with 1,2-dimethylimidazole and 2-methylimidazole: Synthesis, spectroscopic and crystal structure characterization and their superoxide scavenging activities
    Abuhijleh, A. Latif
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 980 (1-3) : 201 - 207
  • [28] One- and Two-Dimensional Cadmium(II) Tetracyanonickelate(II) Coordination Polymers With Imidazole and 2-Methylimidazole Ligands
    Güneş Süheyla Kürkçüoğlu
    Okan Zafer Yeşilel
    İlkay Çaylı
    Orhan Büyükgüngör
    Journal of Inorganic and Organometallic Polymers and Materials, 2011, 21 : 306 - 315
  • [29] Experimental and theoretical evaluation of N-pyridoxal-salicylic acid hydrazide derived copper(II) complex with 2-methylimidazole
    Vishwakarma, Pradeep Kumar
    Jaget, Pushpendra Singh
    Parte, Mahendra Kumar
    Maurya, Ram Charitra
    Rajak, Deepak Kumar
    Chanpuria, Aniteshma
    Shukla, Abhilasha
    Ali, Ahad
    JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS, 2023, 41 (11) : 5305 - 5316
  • [30] Regulated molecular rotor in phase transition materials with switchable dielectric and SHG effect
    Gao, Ya-Fang
    Zhang, Zhi-Xu
    Zhang, Tie
    Su, Chang-Yuan
    Zhang, Wan-Ying
    Fu, Da-Wei
    MATERIALS CHEMISTRY FRONTIERS, 2020, 4 (10) : 3003 - 3012
12345