Selective host-guest interactions on mesoporous TiO2 films modified with carboxymethyl-β-cyclodextrin

被引：28

作者：

Toma, Sergio H. ^{[1
]}

Bonacin, Juliano A. ^{[1
]}

Araki, Koiti ^{[1
]}

Toma, Henrique E. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

来源：

SURFACE SCIENCE | 2006年 / 600卷 / 19期

基金：

巴西圣保罗研究基金会;

关键词：

cyclodextrin; organo-functionalization of surfaces; titanium dioxide; photochemistry; chemisorption; inclusion phenomena;

D O I：

10.1016/j.susc.2006.07.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surface modification of mesoporous nanocrystalline TiO2 films with carboxymethyl-p-cyclodextrin (CMBCD) improves the adsorption of typically non anchoring species, such as bis(4-bromophenylterpyridine)iron(II), by means of host-guest interactions. Such host-guest strategy allows the exploitation of the photochemical properties of the TiO2 surfaces for the selective photodegradation of guest organic species. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：4591 / 4597

页数：7

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