Fe2O3 Nanostructures on Carbon Fabric as Anode Material for High Performance Asymmetric Supercapacitors

被引:8
作者
Wang, Bo [1 ]
Liu, Qi [1 ]
Lu, Yiyun [1 ]
Huang, Liang [2 ,3 ]
机构
[1] Luoyang Inst Sci & Technol, Dept Elect Engn & Automat, Luoyang 471023, Peoples R China
[2] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Peoples R China
[3] Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China
关键词
Supercapacitors; Asymmetric; Fe2O3; MnO2; SOLID-STATE SUPERCAPACITORS; ELECTROLESS DEPOSITION; IRON-OXIDE; FLEXIBLE SUPERCAPACITORS; NEGATIVE ELECTRODES; MNO2; NANOWIRES; NANOSCALE MNO2; ENERGY; NANORODS; STORAGE;
D O I
10.1166/sam.2015.2578
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Supercapacitors (SCs) with asymmetric electrodes structure provide an effective approach to improve the energy density of SCs. We reported a novel anode material based on Fe2O3 nanoflakes grown on carbon fabric which exhibited a high specific capacitance of similar to 386 F/g. To fabricate asymmetric supercapacitors (ASCs), Fe2O3 nanoflakes negative electrodes and MnO2 positive electrodes were assembled together with a separator sandwiched between them. The fabricated ASCs showed a stable performance over a wide voltage range (0-1.6 V) and a high specific capacitance (510 F/g) with high areal capacitance (210 mF/cm(2)). At the meanwhile, a high energy density of 45.3 Wh/kg could be achieved. The fabricated ASCs demonstrated their great potential in energy storage for next-generation hybrid electrical vehicles and other consumer electronics.
引用
收藏
页码:2596 / 2602
页数:7
相关论文
共 52 条
[1]   Examination of the double-layer capacitance of an high specific-area C-cloth electrode as titrated from acidic to alkaline pHs [J].
Andreas, Heather A. ;
Conway, Brian E. .
ELECTROCHIMICA ACTA, 2006, 51 (28) :6510-6520
[2]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[3]   A hybrid Fe3O4-MnO2 capacitor in mild aqueous electrolyte [J].
Brousse, T ;
Belanger, D .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (11) :A244-A248
[4]   Long-term cycling behavior of asymmetric activated carbon/MnO2 aqueous electrochemical supercapacitor [J].
Brousse, Thierry ;
Taberna, Pierre-Louis ;
Crosnier, Olivier ;
Dugas, Romain ;
Guillemet, Philippe ;
Scudeller, Yves ;
Zhou, Yingke ;
Favier, Frederic ;
Belanger, Daniel ;
Simon, Patrice .
JOURNAL OF POWER SOURCES, 2007, 173 (01) :633-641
[5]   Hollow nickel nanocorn arrays as three-dimensional and conductive support for metal oxides to boost supercapacitive performance [J].
Chao, Dongliang ;
Xia, Xinhui ;
Zhu, Changrong ;
Wang, Jin ;
Uu, Jilei ;
Lin, Jianyi ;
Shen, Zexiang ;
Fan, Hong Jin .
NANOSCALE, 2014, 6 (11) :5691-5697
[6]   Preparation and Characterization of Flexible Asymmetric Supercapacitors Based on Transition-Metal-Oxide Nanowire/Single-Walled Carbon Nanotube Hybrid Thin-Film Electrodes [J].
Chen, Po-Chiang ;
Shen, Guozhen ;
Shi, Yi ;
Chen, Haitian ;
Zhou, Chongwu .
ACS NANO, 2010, 4 (08) :4403-4411
[7]   Flexible and cross-linked N-doped carbon nanofiber network for high performance freestanding supercapacitor electrode [J].
Cheng, Yongliang ;
Huang, Liang ;
Xiao, Xu ;
Yao, Bin ;
Yuan, Longyan ;
Li, Tianqi ;
Hu, Zhimi ;
Wang, Bo ;
Wan, Jun ;
Zhou, Jun .
NANO ENERGY, 2015, 15 :66-74
[8]   Fast and reversible surface redox reaction in nanocrystalline vanadium nitride supercapacitors [J].
Choi, Daiwon ;
Blomgren, George E. ;
Kumta, Prashant N. .
ADVANCED MATERIALS, 2006, 18 (09) :1178-+
[9]   Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density [J].
Fan, Zhuangjun ;
Yan, Jun ;
Wei, Tong ;
Zhi, Linjie ;
Ning, Guoqing ;
Li, Tianyou ;
Wei, Fei .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) :2366-2375
[10]   Electroless deposition of nanoscale MnO2 on ultraporous carbon nanoarchitectures:: Correlation of evolving pore-solid structure and electrochemical performance [J].
Fischer, Anne E. ;
Saunders, Matthew P. ;
Pettigrew, Katherine A. ;
Rolison, Debra R. ;
Long, Jeffrey W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (03) :A246-A252