Multifunctional Pd@MOF core-shell nanocomposite as highly active catalyst for p-nitrophenol reduction

被引:104
作者
Wang, Chun [1 ]
Zhang, Haiyan [1 ]
Feng, Cheng [1 ]
Gao, Shutao [1 ]
Shang, Ningzhao [1 ]
Wang, Zhi [1 ]
机构
[1] Agr Univ Hebei, Coll Sci, Baoding 071001, Peoples R China
基金
中国国家自然科学基金;
关键词
Pd@ZIF-8; p-nitrophenol; Catalytic reduction; METAL-ORGANIC FRAMEWORK; SYNERGISTIC CATALYSIS; FACILE SYNTHESIS; 4-NITROPHENOL; NANOCRYSTALS; DEGRADATION; OXIDATION; GOLD;
D O I
10.1016/j.catcom.2015.09.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multifunctional highly dispersed Pd nanoparticles supported on the metal-organic framework core shell nanocomposite (Pd@ZIF-8), was prepared by a preferred strategy. The particles were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, high-resolution transmission electron microscopy and inductively coupled plasma atomic emission spectroscopy. The Pd@ZIF-8 exhibits excellent catalytic activity toward the catalytic reduction of p-nitrophenol to p-aminophenol in the presence of NaBH4 at room temperature. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:29 / 32
页数:4
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