Hydrocarbon Oxygenations with Peroxides Catalyzed by Metal Compounds

被引：185
作者：
Shul'pin, Georgiy B. [1 ]
机构：
[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia
来源：
MINI-REVIEWS IN ORGANIC CHEMISTRY | 2009年 / 6卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
Alkanes; olefins; aromatics; epoxidation; metal-complex catalysis; alkyl hydroperoxides; COMPLEX-CARBOXYLIC-ACID; O-2-H2O2-VANADIUM DERIVATIVE-PYRAZINE-2-CARBOXYLIC ACID; DINUCLEAR MANGANESE(IV) COMPLEX; LIQUID-PHASE OXIDATION; SIGMA-ARYL COMPLEXES; H2O2-VANADIUM COMPLEX-PYRAZINE-2-CARBOXYLIC ACID; H INSERTION REACTIONS; ONE-POT CONVERSION; HYDROGEN-PEROXIDE; SYSTEM HYDROGEN;
D O I：
10.2174/157019309788167738
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent works devoted to the oxygenations of saturated, aromatic as well as olefinic hydrocarbons are surveyed, and the emphasis is made on the author's own publications. Both soluble metal complexes and solid metal compounds catalyze oxidative transformations of hydrocarbons. Hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants. The catalytic systems often include obligatory co-catalysts, for example, nitrogen-containing bases or acids (inorganic, carboxylic or amino acids).
引用
收藏
页码：95 / 104
页数：10
相关论文
共 205 条
  • [31] Mononuclear diastereopure non-heme Fe(II) complexes of pentadentate ligands with pyrrolidinyl moieties: Structural studies, and alkene and sulfide oxidation
    Gosiewska, Silvia
    Lutz, Martin
    Spek, Anthony L.
    Gebbink, Robertus J. M. Klein
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (01) : 405 - 417
  • [32] New phenanthroline iron complexes: Synthesis and catalytic activity in alkane oxidation with hydrogen peroxide
    Gritsenko, O. N.
    Gutkina, E. A.
    Ammon, H.
    Schmittel, M.
    Shteinman, A. A.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 52 (01) : 92 - 96
  • [33] Investigation of a new oxidative catalytic system involving Jacobsen's catalyst in the absence of organic solvents
    Guedes, DFC
    Mac Leod, TCO
    Gotardo, MCAF
    Schiavon, MA
    Yoshida, IVP
    Ciuffi, KJ
    Assis, MD
    [J]. APPLIED CATALYSIS A-GENERAL, 2005, 296 (01) : 120 - 127
  • [34] Oxidation with the ''O-2-H2O2-VO3--pyrazine-2-carboxylic acid'' reagent .6. Oxidation of n-heptane and cyclochexane. Direct determination of alkyl hydroperoxides by gas-liquid chromatography
    Guerreiro, MC
    Schuchardt, U
    Shulpin, GB
    [J]. RUSSIAN CHEMICAL BULLETIN, 1997, 46 (04) : 749 - 754
  • [35] Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source
    Hirai, Yuichirou
    Kojima, Takahiko
    Mizutani, Yasuhisa
    Shiota, Yoshihito
    Yoshizawa, Kazunari
    Fukuzumi, Shunichi
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (31) : 5772 - 5776
  • [36] Alkane hydroxylation catalyzed by a series of mononuclear nonheme iron complexes containing 4-nitropyridine ligands
    Hitomi, Yutaka
    Furukawa, Shinya
    Higuchi, Masakazu
    Shishido, Tetsuya
    Tanaka, Tsunehiro
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 288 (1-2) : 83 - 86
  • [37] Regioselective oxyfunctionalization of unactivated carbons in steroids by a model of cytochrome P-450:: Osmiumporphyrin complex/tert-butyl hydroperoxide system
    Iida, Takashi
    Ogawa, Shoujiro
    Hosoi, Keiji
    Makino, Mitsuko
    Fujimoto, Yasuo
    Goto, Takaaki
    Mano, Nariyasu
    Goto, Junichi
    Hofmann, Alan F.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (03) : 823 - 830
  • [38] Jannini MJDM, 2005, PETROL CHEM+, V45, P413
  • [39] Oxidation of ethyl benzene and diphenyl methane over ordered mesoporous M-MCM-41 (M = Ti, V, Cr): Synthesis, characterization and structure-activity correlations
    Jha, R. K.
    Shylesh, S.
    Bhoware, S. S.
    Singh, A. P.
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 95 (1-3) : 154 - 163
  • [40] Synthesis, characterization and catalytic oxidation activity of zirconium doped K-OMS-2 type manganese oxide materials
    Jothiramalingam, R.
    Viswanathan, B.
    Varadarajan, T. K.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 252 (1-2) : 49 - 55
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