Hydrocarbon Oxygenations with Peroxides Catalyzed by Metal Compounds

被引：185
作者：
Shul'pin, Georgiy B. [1 ]
机构：
[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia
来源：
MINI-REVIEWS IN ORGANIC CHEMISTRY | 2009年 / 6卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
Alkanes; olefins; aromatics; epoxidation; metal-complex catalysis; alkyl hydroperoxides; COMPLEX-CARBOXYLIC-ACID; O-2-H2O2-VANADIUM DERIVATIVE-PYRAZINE-2-CARBOXYLIC ACID; DINUCLEAR MANGANESE(IV) COMPLEX; LIQUID-PHASE OXIDATION; SIGMA-ARYL COMPLEXES; H2O2-VANADIUM COMPLEX-PYRAZINE-2-CARBOXYLIC ACID; H INSERTION REACTIONS; ONE-POT CONVERSION; HYDROGEN-PEROXIDE; SYSTEM HYDROGEN;
D O I：
10.2174/157019309788167738
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent works devoted to the oxygenations of saturated, aromatic as well as olefinic hydrocarbons are surveyed, and the emphasis is made on the author's own publications. Both soluble metal complexes and solid metal compounds catalyze oxidative transformations of hydrocarbons. Hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants. The catalytic systems often include obligatory co-catalysts, for example, nitrogen-containing bases or acids (inorganic, carboxylic or amino acids).
引用
收藏
页码：95 / 104
页数：10
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