Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)

被引：9

作者：

Anufriev, Sergey A. ^{[1
]}

Timofeev, Sergey, V ^{[1
]}

Anisimov, Alexei A. ^{[1
,2
]}

Suponitsky, Kyrill Yu ^{[1
,3
]}

Sivaev, Igor B. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilov Str, Moscow 119991, Russia

[2] Russian Acad Sci, Higher Chem Coll, DI Mendeleev Russian Chem Technol Univ, 9 Miusskaya Sq, Moscow 125047, Russia

[3] GV Plekhanov Russian Univ Econ, Basic Dept Chem Innovat Mat & Technol, 36 Stremyannyi Line, Moscow 117997, Russia

来源：

MOLECULES | 2020年 / 25卷 / 23期

基金：

俄罗斯科学基金会;

关键词：

molecular switches; cobalt bis(dicarbollide); iron bis(dicarbollide); methylsulfanyl derivatives; complexation; X-ray diffraction; COORDINATION POLYMERS; COPPER(I); MERCURY(II); SILVER(I); CHEMISTRY;

D O I：

10.3390/molecules25235745

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Complexation of the 8,8 '-bis(methylsulfanyl) derivatives of cobalt and iron bis(dicarbollides) [8,8 '-(MeS)(2)-3,3 '-M(1,2-C2B9H10)(2)](-) (M = Co, Fe) with copper, silver, palladium and rhodium leads to the formation of the corresponding chelate complexes, which is accompanied by a transition from the transoid to the cisoid conformation of the bis(dicarbollide) complex. This transition is reversible and can be used in design of coordination-driven molecular switches based on transition metal bis(dicarbollide) complexes. The solid-state structures of {(Ph3P)ClPd[8,8 '- (MeS)(2)-3,3 '-Co(1,2-C2B9H10)(2)-kappa(2)-S,S ']} and {(COD)Rh[8,8 '-(MeS)(2)-3,3 '-Co(1,2-C2B9H10)(2)-kappa(2)-S,S ']} were determined by single crystal X-ray diffraction.

引用

页数：11

共 49 条

[41] Synthesis and electrochemical study of 3- and 4-(2-pyridyl)-1,3-benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of bis{(4-(2-pyridyl)-1,3-benzothiazole)copper(ii)} tetraacetate
E. K. Beloglazkina
I. V. Yudin
A. G. Mazhuga
A. A. Moiseeva
S. V. Zatonskii
N. V. Zyk
Russian Chemical Bulletin, 2008, 57 : 577 - 584
[42] METAL-COMPLEXES OF TETRAPYRROLE LIGANDS .39. EFFECTS OF STERIC CROWDING ON PORPHYRIN CONFORMATION - SYNTHESIS, CRYSTAL-STRUCTURE AND MOLECULAR STEREOCHEMISTRY OF MU-OXO-BIS[(5,15-DIMETHYL-2,3,7,8,12,13,17,18-OCTAETHYLPORPHINATO)IRON(III)]
LAY, KL
BUCHLER, JW
KENNY, JE
SCHEIDT, WR
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1986, 123 (02): : 91 - 97
[43] ORGANOMETALLIC COMPOUNDS OF THE LANTHANOIDS .89. CYCLOOCTATETRAENYL COMPLEXES OF THE EARLY TRANSITION-METALS AND LANTHANOIDS .6. (CYCLOOCTATETRAENYL)[N,N'-BIS(TRIMETHYLSILYL)BENZAMIDINATO]PHOSHINATO] AND (CYCLOOCTATETRAENYL)(DIPHENYLBIS(TRIMETHYLSILYLIMIDO)-PHOSPHINATO] COMPLEXES OF THE RARE-EARTHS - X-RAY STRUCTURAL-ANALYSES OF (C8H8)TM[PHC(NSIME(3))(2)](THF), (C8H8)LU[4-MEOC(6)H(4)C(NSIME(3))(2)](THF), AND (C8H8)ND[PH(2)P(NSIME(3))(2)](THF)
SCHUMANN, H
WINTERFELD, J
HEMLING, H
HAHN, FE
REICH, P
BRZEZINKA, KW
EDELMANN, FT
KILIMANN, U
SCHAFER, M
HERBSTIRMER, R
CHEMISCHE BERICHTE, 1995, 128 (04) : 395 - 404
[44] The radical ions of acenaphtho[1,2-b][1,4]dithiine derivatives and acenaphtho[1,2-b][1,4]oxathiine:: Solution EPR and ENDOR studies.: The X-ray crystal structures of 8,9-bis(methylsulfanyl)acenaphtho[1,2-b][1,4]dithiine and its complexes with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ), 2,5-dibromo-TCNQ and iodine
Bryce, MR
Lay, AK
Chesney, A
Batsanov, AS
Howard, JAK
Buser, U
Gerson, F
Merstetter, P
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999, (04): : 755 - 763
[45] Tris (4-bromo-1H-pyraaol-1-yl)borato derivatives of first-row transition and group 12 and 14 metals. X-ray crystal structure of [HB(4Brpz)(3)](2)Cd. Cd-113 solution NMR study of bis[poly(pyrazolyl)borato] cadmium complexes
Lobbia, GG
Bovio, B
Santini, C
Cecchi, P
Pettinari, C
Marchetti, F
POLYHEDRON, 1998, 17 (01) : 17 - 26
[46] Synthesis of 11-vertex cobalt bis(diphenylphosphine) complexes based on medium-size non-icosahedral carborane 5,6-nido-C2B8H12. Molecular structure of complex [1,1-{κ2-1′,2′-Ph2P(CH2)2PPh2}-1-H-isonido-1,2,4-CoC2B8H10]
Balagurova, E. V.
Tyurin, A. P.
Godovikov, I. A.
Dolgushin, F. M.
Chizhevsky, I. T.
RUSSIAN CHEMICAL BULLETIN, 2024, 73 (10) : 2890 - 2899
[47] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .71. OPEN-CHAIN AND CYCLIC ORGANORHENIUM COMPLEXES OF PI-AROMATIC LIGANDS - OXYGEN-CONTAINING, SULFUR-CONTAINING, AND SELENIUM-CONTAINING DERIVATIVES - STRONG STATIC TRANS INFLUENCE IN THE CRYSTAL AND MOLECULAR-STRUCTURE OF DI-MU-SULFIDO-BIS[OXO(ETA-5-PENTAMETHYL-CYCLOPENTADIENYL)RHENIUM(V)]
HERRMANN, WA
JUNG, KA
HERDTWECK, E
CHEMISCHE BERICHTE-RECUEIL, 1989, 122 (11): : 2041 - 2048
[48] METAL PI-COMPLEXES OF BENZENE-DERIVATIVES .48. DIMETHYLPHOSPHANO DERIVATIVES OF BIS(BENZENE) CHROMIUM AS MONODENTATE AND CHELATING LIGANDS AT MU-ETHYLIDYNE-NONA(CARBONYL)-TRI(COBALT) - SYNTHESIS VIA ETC-AUTOCATALYSIS, CRYSTAL-STRUCTURE DETERMINATION AND REDOX BEHAVIOR OF [(ME(2)P-ETA(6)-C6H5)(ETA(6)-C6H6)CR[(MU-MEC)CO-3(CO)(8)], [(ME(2)P-ETA(6)-C6H5)(2)CR][(MU-MEC)CO-3(CO)(8)](2) AND [(ME(2)P-ETA(6)-C6H5)(2)CR][(MU-MEC)CO-3(CO)(7)]
ELSCHENBROICH, C
ISENBURG, T
BEHRENDT, A
FRENZEN, G
HARMS, K
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 501 (1-2) : 129 - 144
[49] BINUCLEAR NICKEL(II) AND COBALT(II) COMPLEXES OF SEXADENTATE (N-6) PHTHALAZINE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF [MU-1,4-BIS((6-METHYLPYRIDINE-2-CARBOXALDIMINO)AMINO)PHTHALAZINE-N4,N3,MU-N1,MU-N1A,N3A,N4A](MU-CHLORO)TETRAAQUODICOBALT(II) TRICHLORIDE-4.3-WATER, CO2C22H28CL4N8O4.4.3H2O, AND [MU-1,4-BIS((6-METHYLPYRIDINE-2-CARBOXALDIMINO)AMINO)PHTHALAZINE-N4,N3,MU-N1,MU-N1A,N3A,N4A](MU-CHLORO)TETRAAQUODINICKEL(II) TRICHLORIDE-4.6-WATER, NI2C22H28CL4N8O4.4.6H2O[
WEN, T
THOMPSON, LK
LEE, FL
GABE, EJ
INORGANIC CHEMISTRY, 1988, 27 (23) : 4190 - 4196

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