Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)

被引：9

作者：

Anufriev, Sergey A. ^{[1
]}

Timofeev, Sergey, V ^{[1
]}

Anisimov, Alexei A. ^{[1
,2
]}

Suponitsky, Kyrill Yu ^{[1
,3
]}

Sivaev, Igor B. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilov Str, Moscow 119991, Russia

[2] Russian Acad Sci, Higher Chem Coll, DI Mendeleev Russian Chem Technol Univ, 9 Miusskaya Sq, Moscow 125047, Russia

[3] GV Plekhanov Russian Univ Econ, Basic Dept Chem Innovat Mat & Technol, 36 Stremyannyi Line, Moscow 117997, Russia

来源：

MOLECULES | 2020年 / 25卷 / 23期

基金：

俄罗斯科学基金会;

关键词：

molecular switches; cobalt bis(dicarbollide); iron bis(dicarbollide); methylsulfanyl derivatives; complexation; X-ray diffraction; COORDINATION POLYMERS; COPPER(I); MERCURY(II); SILVER(I); CHEMISTRY;

D O I：

10.3390/molecules25235745

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Complexation of the 8,8 '-bis(methylsulfanyl) derivatives of cobalt and iron bis(dicarbollides) [8,8 '-(MeS)(2)-3,3 '-M(1,2-C2B9H10)(2)](-) (M = Co, Fe) with copper, silver, palladium and rhodium leads to the formation of the corresponding chelate complexes, which is accompanied by a transition from the transoid to the cisoid conformation of the bis(dicarbollide) complex. This transition is reversible and can be used in design of coordination-driven molecular switches based on transition metal bis(dicarbollide) complexes. The solid-state structures of {(Ph3P)ClPd[8,8 '- (MeS)(2)-3,3 '-Co(1,2-C2B9H10)(2)-kappa(2)-S,S ']} and {(COD)Rh[8,8 '-(MeS)(2)-3,3 '-Co(1,2-C2B9H10)(2)-kappa(2)-S,S ']} were determined by single crystal X-ray diffraction.

引用

页数：11

共 49 条

[31] Bonding interactions of a molecular pair of tweezers with transition metals.: Theoretical study of bis(η2-alkyne) complexes of copper(I), silver(I), and gold(I)
Kovács, A
Frenking, G
ORGANOMETALLICS, 1999, 18 (05) : 887 - 894
[32] 2,6-diformyl-4-tert-butylphenol bis(8-quinolylhydrazone) and its transition metal complexes:: Physicochemical study and quantum-chemical simulation
Popova, L. D.
Levchenkov, S. I.
Shcherbakov, I. N.
Tupolova, Yu. P.
Kogan, V. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (01) : 90 - 100
[33] 2,6-Diformyl-4-tert-butylphenol bis(8-quinolylhydrazone) and its transition metal complexes: Physicochemical study and quantum-chemical simulation
L. D. Popov
S. I. Levchenkov
I. N. Shcherbakov
Yu. P. Tupolova
V. A. Kogan
Russian Journal of General Chemistry, 2008, 78 : 90 - 100
[34] INVESTIGATIONS ON REACTIVITY OF METAL-PI-COMPLEXES .8. PI-CYCLOPENTADIENYL-IRON-BIS(TRIPHENYLPHOSPHITE)-NONAMETHYLTETRASTANNANE - TRANSITION-METAL COMPLEX WITH A SN4-CLUSTER AS LIGAND
KLAUI, W
WERNER, H
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 54 (JUN16) : 331 - 340
[35] Syntheses of the B(8)-hydroxy- and B(8,8′)-dihydroxy-derivatives of the bis(1,2-dicarbollido)-3-colbalt(1-)ate ion by its reductive acetoxylation and hydroxylation:: molecular structure of [8,8′-μ-CH3C(O)2(1,2-C2B9H10)2-3-Co]0 zwitterion determined by X-ray diffraction analysis
Plesek, J
Grüner, B
Báca, J
Fusek, J
Císarová, I
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 649 (02) : 181 - 190
[36] Functionalized cobalt bis(dicarbollide) ions as selective extraction reagents for removal of M2+ and M3+ cations from nuclear waste, crystal and molecular structures of the [8,8′-μ-CIP(O)(O)2(1,2-C2B9H10)2-3,3′-Co]HN(C2H5)3 and [8,8′-μ-Et2NP(O)(O)2 (1,2-C2B9H10)2-3,3′-Co](HN(CH3)3)
Plesek, J
Grüner, B
Císarová, I
Báca, J
Selucky, P
Rais, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 657 (1-2) : 59 - 70
[37] COMPLEXES OF COBALT(II), NICKEL(II) AND COPPER(II) WITH A PENTADENTATE BIS(BETA-AMINO KETONE) - CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA(4,4,12,12-TETRAMETHYL-5,8,11-TRIAZAPENTADECANE-2,14-DIONE)COBALT(III) PERCHLORATE HYDRATE
MORGAN, KR
GAINSFORD, GJ
CURTIS, NF
AUSTRALIAN JOURNAL OF CHEMISTRY, 1982, 35 (06) : 1105 - 1117
[38] CHALCOGENOLATES AND THEIR DERIVATIVES .8. COMPLEXES OF TELLURIUM WITH HALIDE AND DITHIO LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF BROMO-BIS(DIMETHYLDITHIOCARBAMATO-S,S')TELLURIUM(IV) TETRABROMO-(DIMETHYLDITHIOCARBAMATO-S,S')TELLURATE(IV) DIOXANE SOLVATE
SCHNABEL, W
VONDEUTEN, K
KLAR, G
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1982, 13 (03): : 345 - 355
[39] STUDY OF THE STRUCTURE OF COMPLEXES OF THE TRANSITION-METALS WITH PARAMAGNETIC LIGANDS .1. THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS-(2,2,5,5,-TETRAMETHYL-3-AMINOPYRROLIDINE-1-IMINOXYL-O-VANILLATO)COPPER(II)
GUSEINOVA, MK
MAMEDOV, SD
JOURNAL OF STRUCTURAL CHEMISTRY, 1978, 19 (03) : 445 - 450
[40] Synthesis and electrochemical study of 3-and 4-(2-pyridyl)-1,3-benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of bis{(4-(2-pyridyl)-1,3-benzothiazole)copper(II)} tetraacetate
Beloglazkina, E. K.
Yudin, I. V.
Mazhuga, A. G.
Moiseeva, A. A.
Zatonskii, S. V.
Zyk, N. V.
RUSSIAN CHEMICAL BULLETIN, 2008, 57 (03) : 577 - 584

← 1 2 3 4 5 →