Mechanistic insights into the reduction of graphene oxide addressing its surfaces

被引:19
作者
Eigler, Siegfried [1 ,2 ]
机构
[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-90762 Furth, Germany
[2] Univ Erlangen Nurnberg, Inst Adv Mat & Proc ZMP, D-90762 Furth, Germany
关键词
GRAPHITE OXIDE; CARBON FRAMEWORK; FUNCTIONALIZATION; CHEMISTRY; DEFECTS;
D O I
10.1039/c4cp03168g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Both sides of a graphene oxide (ai-GO) layer are decorated with functional groups. For the first time it is demonstrated that an effective reduction of ai-GO to graphene can be performed, even if the reducing agent can access only one side of ai-GO. A general reduction mechanism is proposed.
引用
收藏
页码:19832 / 19835
页数:4
相关论文
共 28 条
[1]  
Brodie B., 1855, ANN CHIM PHYS, V45, P351
[2]   Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies [J].
Cancado, L. G. ;
Jorio, A. ;
Martins Ferreira, E. H. ;
Stavale, F. ;
Achete, C. A. ;
Capaz, R. B. ;
Moutinho, M. V. O. ;
Lombardo, A. ;
Kulmala, T. S. ;
Ferrari, A. C. .
NANO LETTERS, 2011, 11 (08) :3190-3196
[3]   NMR-Based Structural Modeling of Graphite Oxide Using Multidimensional 13C Solid-State NMR and ab Initio Chemical Shift Calculations [J].
Casabianca, Leah B. ;
Shaibat, Medhat A. ;
Cai, Weiwei W. ;
Park, Sungjin ;
Piner, Richard ;
Ruoff, Rodney S. ;
Ishii, Yoshitaka .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5672-5676
[4]   Graphene-Based Nanomaterials: Synthesis, Properties, and Optical and Optoelectronic Applications [J].
Chang, Haixin ;
Wu, Hongkai .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (16) :1984-1997
[5]  
Charpy G, 1909, CR HEBD ACAD SCI, V148, P920
[6]   Chemical reduction of graphene oxide: a synthetic chemistry viewpoint [J].
Chua, Chun Kiang ;
Pumera, Martin .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (01) :291-312
[7]   Biomedical Applications of Graphene and Graphene Oxide [J].
Chung, Chul ;
Kim, Young-Kwan ;
Shin, Dolly ;
Ryoo, Soo-Ryoon ;
Hong, Byung Hee ;
Min, Dal-Hee .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (10) :2211-2224
[8]   One-pot reduction of graphene oxide at subzero temperatures [J].
Cui, Peng ;
Lee, Junghyun ;
Hwang, Eunhee ;
Lee, Hyoyoung .
CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12370-12372
[9]   Pristine Graphite Oxide [J].
Dimiev, Ayrat ;
Kosynkin, Dmitry V. ;
Alemany, Lawrence B. ;
Chaguine, Pavel ;
Tour, James M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (05) :2815-2822
[10]   Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].
Eda, Goki ;
Fanchini, Giovanni ;
Chhowalla, Manish .
NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274